(Z)-4-Chloro-N-(1-{2-[3-(4-chlorobenzoyl)ureido]ethyl}imidazolidin-2- ylidene)benzamide

Dalina Adan, Suhaila Sapari, Siti Nadiah Halim, Bohari Mohd. Yamin

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The title compound, C20H19Cl2N 5O2S, was obtained from the reaction of 4-chlorobenzoyl isothiocyanate with diethylenetriamine. The imidazolidine ring is slightly twisted with an N - C - C - N torsion angle of 15.4 (4)°, while the thiourea moiety maintains its trans-cis geometry. The molecule is stabilized by intramolecular N - H⋯O hydrogen bonds. The crystal structure features N - H⋯O, N - H⋯S and C - H⋯O hydrogen bonds and π-π interactions between benzene rings with a centroid-centroid distance of 3.607 (3) Å.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume68
Issue number7
DOIs
Publication statusPublished - Jul 2012

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centroids
Hydrogen bonds
Imidazolidines
hydrogen bonds
Thiourea
Thioureas
rings
thioureas
Benzene
Torsional stress
torsion
Crystal structure
benzene
crystal structure
Molecules
Geometry
geometry
molecules
interactions
benzamide

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

(Z)-4-Chloro-N-(1-{2-[3-(4-chlorobenzoyl)ureido]ethyl}imidazolidin-2- ylidene)benzamide. / Adan, Dalina; Sapari, Suhaila; Halim, Siti Nadiah; Mohd. Yamin, Bohari.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 68, No. 7, 07.2012.

Research output: Contribution to journalArticle

Adan, Dalina ; Sapari, Suhaila ; Halim, Siti Nadiah ; Mohd. Yamin, Bohari. / (Z)-4-Chloro-N-(1-{2-[3-(4-chlorobenzoyl)ureido]ethyl}imidazolidin-2- ylidene)benzamide. In: Acta Crystallographica Section E: Structure Reports Online. 2012 ; Vol. 68, No. 7.
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AU - Halim, Siti Nadiah

AU - Mohd. Yamin, Bohari

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