Utilization of Core Oil Palm Trunk Waste to Methyl Levulinate: Physical and Chemical Characterizations

Noorhasmiera Abu Jahar, Fei ling Pua, Wong Jia Chyi, Marhaini Mostapha, Sarani Zakaria, Chin Hua Chia, Sharifah Nabihah Syed Jaafar

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Core oil palm trunk (COPT) is a lignocellulosic waste that poses as an alternative carbon source in bio-chemical and bio-fuel production. The bulk of free sugar present in its sap renders COPT as a potential starting material in the synthesis of methyl levulinate (ML). In this study, the effect of different sap extractions on COPT and synthesised methyl levulinate respectively was analysed. COPT sap was extracted using two different methods of blending and pressing, followed by the methanolysis reaction. The high performance liquid chromatography (HPLC) results for both extraction methods have revealed that glucose is the primary sugar found in the sap. However, the total sugar concentration obtained from the pressing extraction method was found to be higher at 22.14 g/L, compared to blending extraction method at 20.23 g/L. Meanwhile, synthesized methyl levulinate was identified from the methanolysis of COPT sap in all type of catalysts (i.e. 0.5 M HCl, 1 M HCl, 0.5 M H2SO4 and 1 M H2SO4). It is worth noting that the isolated and highest concentration of methyl levulinate was obtained when catalysed by 1 M H2SO4 and can be clearly seen on the NMR spectrum.

Original languageEnglish
Pages (from-to)1-6
Number of pages6
JournalWaste and Biomass Valorization
DOIs
Publication statusAccepted/In press - 14 Sep 2017

Fingerprint

Palm oil
extraction method
Sugars
oil
sugar
High performance liquid chromatography
biofuel
Glucose
nuclear magnetic resonance
liquid chromatography
glucose
catalyst
Nuclear magnetic resonance
chemical
Catalysts
Carbon
carbon

Keywords

  • Cellulose
  • Extraction
  • Free sugars
  • Methyl levulinate

ASJC Scopus subject areas

  • Environmental Engineering
  • Renewable Energy, Sustainability and the Environment
  • Waste Management and Disposal

Cite this

Utilization of Core Oil Palm Trunk Waste to Methyl Levulinate : Physical and Chemical Characterizations. / Abu Jahar, Noorhasmiera; Pua, Fei ling; Chyi, Wong Jia; Mostapha, Marhaini; Zakaria, Sarani; Chia, Chin Hua; Syed Jaafar, Sharifah Nabihah.

In: Waste and Biomass Valorization, 14.09.2017, p. 1-6.

Research output: Contribution to journalArticle

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