trans-cis S-benzyl dithiocarbazate

S. Shanmuga Sundara Raj, Bohari Mohd. Yamin, Yusrabbil A. Yussof, M. T H Tarafder, Hoong Kun Fun, K. A. Grouse

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

In the crystal structure of C8H10N2S2, the molecules are linked by hydrogen bonds between the iminogroup and the thione-S atoms to form a chain. The dithiocarbazate moiety is rotated by 85.8° with respect to the phenyl ring. The cis-trans conformation is observed in unsubstituted esters and trans-cis in substituted esters. Two conformers of S-methyl dithiocarbazate were obtained in solid state by recrystallization from ethanol at room temperature. The H atom attached to the imino N atom acts as the hydrogen-bond donor.

Original languageEnglish
Pages (from-to)1236-1237
Number of pages2
JournalActa Crystallographica, Section C: Crystal Structure Communications
Volume56
Issue number10
DOIs
Publication statusPublished - Oct 2000

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Hydrogen
Esters
Thiones
Atoms
esters
Hydrogen bonds
hydrogen bonds
atoms
Ethanol
Temperature
Conformations
ethyl alcohol
Crystal structure
solid state
crystal structure
Molecules
rings
room temperature
molecules

ASJC Scopus subject areas

  • Structural Biology
  • Condensed Matter Physics

Cite this

Shanmuga Sundara Raj, S., Mohd. Yamin, B., Yussof, Y. A., Tarafder, M. T. H., Fun, H. K., & Grouse, K. A. (2000). trans-cis S-benzyl dithiocarbazate. Acta Crystallographica, Section C: Crystal Structure Communications, 56(10), 1236-1237. https://doi.org/10.1107/S0108270100009276

trans-cis S-benzyl dithiocarbazate. / Shanmuga Sundara Raj, S.; Mohd. Yamin, Bohari; Yussof, Yusrabbil A.; Tarafder, M. T H; Fun, Hoong Kun; Grouse, K. A.

In: Acta Crystallographica, Section C: Crystal Structure Communications, Vol. 56, No. 10, 10.2000, p. 1236-1237.

Research output: Contribution to journalArticle

Shanmuga Sundara Raj, S, Mohd. Yamin, B, Yussof, YA, Tarafder, MTH, Fun, HK & Grouse, KA 2000, 'trans-cis S-benzyl dithiocarbazate', Acta Crystallographica, Section C: Crystal Structure Communications, vol. 56, no. 10, pp. 1236-1237. https://doi.org/10.1107/S0108270100009276
Shanmuga Sundara Raj S, Mohd. Yamin B, Yussof YA, Tarafder MTH, Fun HK, Grouse KA. trans-cis S-benzyl dithiocarbazate. Acta Crystallographica, Section C: Crystal Structure Communications. 2000 Oct;56(10):1236-1237. https://doi.org/10.1107/S0108270100009276
Shanmuga Sundara Raj, S. ; Mohd. Yamin, Bohari ; Yussof, Yusrabbil A. ; Tarafder, M. T H ; Fun, Hoong Kun ; Grouse, K. A. / trans-cis S-benzyl dithiocarbazate. In: Acta Crystallographica, Section C: Crystal Structure Communications. 2000 ; Vol. 56, No. 10. pp. 1236-1237.
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AU - Fun, Hoong Kun

AU - Grouse, K. A.

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