[TiO2-SiO2] Polymer Electrolytes: In Situ Preparation and Characterization

Oon Lee Kang, Azizan Ahmad, Nur Hasyareeda Hassan, Usman Ali Rana

Research output: Contribution to journalArticle

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Abstract

In the present research, [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes were first prepared through simple stepwise in situ techniques: sol-gel technique and solution-cast technique. [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes were then characterized through different experimental techniques. [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes had exhibited significant structural changes upon different salt concentrations. In the present investigation, [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes had attained maximum ionic conductivities (σ 10-7 S/cm at ambient temperature; 10-4 S/cm at 100°C) upon 25 wt.% salt insertion. [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes had exhibited distinct conduction mechanisms in similar experimental configuration. [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes had exhibited different stability characteristics over certain operational condition.

Original languageEnglish
Article number9838067
JournalInternational Journal of Polymer Science
Volume2016
DOIs
Publication statusPublished - 2016

Fingerprint

Electrolytes
Polymers
Salts
Ionic conductivity
Sol-gels
TiO2-SiO2
lithium perchlorate
Temperature

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

[TiO2-SiO2] Polymer Electrolytes : In Situ Preparation and Characterization. / Kang, Oon Lee; Ahmad, Azizan; Hassan, Nur Hasyareeda; Rana, Usman Ali.

In: International Journal of Polymer Science, Vol. 2016, 9838067, 2016.

Research output: Contribution to journalArticle

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