The production of green polymer - Hyperbranched curable palm oil oleic acid

Mek Zah Salleh, Khairiah Badri, Rida Tajau, Nik Ghazali Salleh

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Palm oil is one of the main raw materials available in the country. Hence, the diversification of palm oil derivatives into new products has been given priority. The development of new radiation curable materials for applications in radiation ultraviolet (UV) or electron beam (EB) curing technology is an important research area. The hyperbranched curable polyurethane acrylate (HBPUA) from oleic acid of palm oil has been synthesized through a threestep reaction. Dipentaerythritol was initially reacted with 2, 2-bis (hydroxymethyl) propionic acid in a solution medium aided by p-toluene sulfonic acid as a catalyst to form hyperbranched polyol polyester first generation (HBP-1). HBP-1 then used as the core and reacted with palm oil oleic acid to form the hyperbranched polyol polyester second generation (HBP-2). HBPUA was prepared by reacting HBP-2 resin with diisocyanate and hydroxyl-containing acrylate monomer with the presence of 0.1-2 wt% dibutyltin dilaurate as a catalyst. The reaction was confirmed by several analytical data namely hydroxyl value (OHV), fourier transform infrared (FTIR), gel permeation chromatography (GPC) and nuclear magnetic resonance (NMR) analyses. The HBPUA was easily curable when subjected to EB radiation. The thermal decomposition of HBPUA showed good thermal stability up to 450 °C.

Original languageEnglish
Title of host publicationAdvanced Materials Research
PublisherTrans Tech Publications Ltd
Pages197-200
Number of pages4
Volume1024
ISBN (Print)9783038352136
DOIs
Publication statusPublished - 2014
Event3rd International Conference on the Advancement of Materials and Nanotechnology, ICAMN 3 2013 - Penang
Duration: 19 Nov 201321 Nov 2013

Publication series

NameAdvanced Materials Research
Volume1024
ISSN (Print)10226680
ISSN (Electronic)16628985

Other

Other3rd International Conference on the Advancement of Materials and Nanotechnology, ICAMN 3 2013
CityPenang
Period19/11/1321/11/13

Fingerprint

Palm oil
Oleic acid
Polyurethanes
Polyols
Polymers
Polyesters
Electron beams
Radiation
Propionic acid
Catalysts
Gel permeation chromatography
Ultraviolet radiation
Toluene
Curing
Fourier transforms
Raw materials
Pyrolysis
Thermodynamic stability
Resins
Monomers

Keywords

  • Hyperbranched polymers
  • Oleic acid
  • Palm oil
  • Radiation

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Salleh, M. Z., Badri, K., Tajau, R., & Salleh, N. G. (2014). The production of green polymer - Hyperbranched curable palm oil oleic acid. In Advanced Materials Research (Vol. 1024, pp. 197-200). (Advanced Materials Research; Vol. 1024). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/AMR.1024.197

The production of green polymer - Hyperbranched curable palm oil oleic acid. / Salleh, Mek Zah; Badri, Khairiah; Tajau, Rida; Salleh, Nik Ghazali.

Advanced Materials Research. Vol. 1024 Trans Tech Publications Ltd, 2014. p. 197-200 (Advanced Materials Research; Vol. 1024).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Salleh, MZ, Badri, K, Tajau, R & Salleh, NG 2014, The production of green polymer - Hyperbranched curable palm oil oleic acid. in Advanced Materials Research. vol. 1024, Advanced Materials Research, vol. 1024, Trans Tech Publications Ltd, pp. 197-200, 3rd International Conference on the Advancement of Materials and Nanotechnology, ICAMN 3 2013, Penang, 19/11/13. https://doi.org/10.4028/www.scientific.net/AMR.1024.197
Salleh MZ, Badri K, Tajau R, Salleh NG. The production of green polymer - Hyperbranched curable palm oil oleic acid. In Advanced Materials Research. Vol. 1024. Trans Tech Publications Ltd. 2014. p. 197-200. (Advanced Materials Research). https://doi.org/10.4028/www.scientific.net/AMR.1024.197
Salleh, Mek Zah ; Badri, Khairiah ; Tajau, Rida ; Salleh, Nik Ghazali. / The production of green polymer - Hyperbranched curable palm oil oleic acid. Advanced Materials Research. Vol. 1024 Trans Tech Publications Ltd, 2014. pp. 197-200 (Advanced Materials Research).
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