Synthesis, spectral characterization and crystal structure of a novel trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)- cyclohexylthiosemicarbazone (H2PACT)

M. A. Salam, M. A. Affan, Fasihuddin B. Ahmad, I. Jusoh, Mustaffa B. Shamsuddin, Bohari Mohd. Yamin, Yang Farina Abdul Aziz

Research output: Contribution to journalArticle

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Abstract

A new trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) ligand was synthesized and characterized by elemental analyses, molar conductivity, UV-Vis, FT-IR, 1H, 119Sn NMR spectroscopy and single crystal X-ray study. Single crystal X-ray diffraction data revealed that this complex was trinuclear cyclic fashion with the pyruvic acid-N(4)-cyclohexylthiosemicarbazone ligand. In the trinuclear di-n-butyltin(IV) complex, the ligand (H2PACT) is coordinated to the central tin(IV) atoms via the carboxylato-O, the azomethine-N and the thiolato-S atoms. The trinuclear tin system is formed by the bridges through the carbonyl oxygen atom of the carboxylate moieties and making the tin atom of seven coordinated in distorted pentagonal bipyramidal geometry. Single crystal X-ray data indicates that the complex (1) crystallized in cubic system with space group I-43d, a = b = c = 30.3273(17) , α = β = γ = 90°, Z = 16, μ(MoKα) = 1.209 mm-1, F(000) = 12,144, and final R1 = 0.0390, wR2 = 0.0843 for observed reflections 4582(I > 2σ(I)).

Original languageEnglish
Pages (from-to)4202-4206
Number of pages5
JournalJournal of Organometallic Chemistry
Volume696
Issue number26
DOIs
Publication statusPublished - 1 Jan 2012

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Tin
Pyruvic Acid
tin
Crystal structure
Ligands
Atoms
ligands
acids
crystal structure
Acids
single crystals
Single crystals
synthesis
X-Rays
atoms
x rays
X-Ray Diffraction
X rays
carboxylates
oxygen atoms

Keywords

  • Crystal structure
  • Pyruvic acid-N(4)- cyclohexylthiosemicarbazone
  • Spectral analysis
  • Trinuclear di-n-butyltin(IV) complex

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Biochemistry

Cite this

Synthesis, spectral characterization and crystal structure of a novel trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)- cyclohexylthiosemicarbazone (H2PACT). / Salam, M. A.; Affan, M. A.; Ahmad, Fasihuddin B.; Jusoh, I.; Shamsuddin, Mustaffa B.; Mohd. Yamin, Bohari; Abdul Aziz, Yang Farina.

In: Journal of Organometallic Chemistry, Vol. 696, No. 26, 01.01.2012, p. 4202-4206.

Research output: Contribution to journalArticle

Salam, M. A. ; Affan, M. A. ; Ahmad, Fasihuddin B. ; Jusoh, I. ; Shamsuddin, Mustaffa B. ; Mohd. Yamin, Bohari ; Abdul Aziz, Yang Farina. / Synthesis, spectral characterization and crystal structure of a novel trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)- cyclohexylthiosemicarbazone (H2PACT). In: Journal of Organometallic Chemistry. 2012 ; Vol. 696, No. 26. pp. 4202-4206.
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abstract = "A new trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) ligand was synthesized and characterized by elemental analyses, molar conductivity, UV-Vis, FT-IR, 1H, 119Sn NMR spectroscopy and single crystal X-ray study. Single crystal X-ray diffraction data revealed that this complex was trinuclear cyclic fashion with the pyruvic acid-N(4)-cyclohexylthiosemicarbazone ligand. In the trinuclear di-n-butyltin(IV) complex, the ligand (H2PACT) is coordinated to the central tin(IV) atoms via the carboxylato-O, the azomethine-N and the thiolato-S atoms. The trinuclear tin system is formed by the bridges through the carbonyl oxygen atom of the carboxylate moieties and making the tin atom of seven coordinated in distorted pentagonal bipyramidal geometry. Single crystal X-ray data indicates that the complex (1) crystallized in cubic system with space group I-43d, a = b = c = 30.3273(17) , α = β = γ = 90°, Z = 16, μ(MoKα) = 1.209 mm-1, F(000) = 12,144, and final R1 = 0.0390, wR2 = 0.0843 for observed reflections 4582(I > 2σ(I)).",
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AU - Salam, M. A.

AU - Affan, M. A.

AU - Ahmad, Fasihuddin B.

AU - Jusoh, I.

AU - Shamsuddin, Mustaffa B.

AU - Mohd. Yamin, Bohari

AU - Abdul Aziz, Yang Farina

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N2 - A new trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) ligand was synthesized and characterized by elemental analyses, molar conductivity, UV-Vis, FT-IR, 1H, 119Sn NMR spectroscopy and single crystal X-ray study. Single crystal X-ray diffraction data revealed that this complex was trinuclear cyclic fashion with the pyruvic acid-N(4)-cyclohexylthiosemicarbazone ligand. In the trinuclear di-n-butyltin(IV) complex, the ligand (H2PACT) is coordinated to the central tin(IV) atoms via the carboxylato-O, the azomethine-N and the thiolato-S atoms. The trinuclear tin system is formed by the bridges through the carbonyl oxygen atom of the carboxylate moieties and making the tin atom of seven coordinated in distorted pentagonal bipyramidal geometry. Single crystal X-ray data indicates that the complex (1) crystallized in cubic system with space group I-43d, a = b = c = 30.3273(17) , α = β = γ = 90°, Z = 16, μ(MoKα) = 1.209 mm-1, F(000) = 12,144, and final R1 = 0.0390, wR2 = 0.0843 for observed reflections 4582(I > 2σ(I)).

AB - A new trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) ligand was synthesized and characterized by elemental analyses, molar conductivity, UV-Vis, FT-IR, 1H, 119Sn NMR spectroscopy and single crystal X-ray study. Single crystal X-ray diffraction data revealed that this complex was trinuclear cyclic fashion with the pyruvic acid-N(4)-cyclohexylthiosemicarbazone ligand. In the trinuclear di-n-butyltin(IV) complex, the ligand (H2PACT) is coordinated to the central tin(IV) atoms via the carboxylato-O, the azomethine-N and the thiolato-S atoms. The trinuclear tin system is formed by the bridges through the carbonyl oxygen atom of the carboxylate moieties and making the tin atom of seven coordinated in distorted pentagonal bipyramidal geometry. Single crystal X-ray data indicates that the complex (1) crystallized in cubic system with space group I-43d, a = b = c = 30.3273(17) , α = β = γ = 90°, Z = 16, μ(MoKα) = 1.209 mm-1, F(000) = 12,144, and final R1 = 0.0390, wR2 = 0.0843 for observed reflections 4582(I > 2σ(I)).

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