Synthesis of borylated porphyrin and bromo-porphyrin as building blocks for light harvesting antenna molecule

Nuur Haziqah Mohd Radzuan, Nurul Izzaty Hassan, Muntaz Abu Bakar

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

The building blocks for synthesis of light harvesting antenna which are 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane)-10,20-diphenylporphyrin, 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane)-10,20-dihexylporphyrin and 5,10,15,20-Tetra-(bromophenyl)porphyrin were synthesized. Borylated porphyrin was synthesized by Suzuki coupling reaction between A2BC bromo-porphyrin and pinacolborane. Whereas 5,10,15,20-Tetra-(bromophenyl) porphyrin was synthesized by Lindsey condensation reaction between pyrrole and 4-bromobenzaldehyde. 1H-NMR, 13C-NMR spectroscopy and UV-visible spectroscopy confirmed the successful formation of all compounds.

Original languageEnglish
Title of host publication2017 UKM FST Postgraduate Colloquium
Subtitle of host publicationProceedings of the University Kebangsaan Malaysia, Faculty of Science and Technology 2017 Postgraduate Colloquium
PublisherAmerican Institute of Physics Inc.
Volume1940
ISBN (Electronic)9780735416321
DOIs
Publication statusPublished - 4 Apr 2018
Event2017 UKM FST Postgraduate Colloquium - Selangor, Malaysia
Duration: 12 Jul 201713 Jul 2017

Other

Other2017 UKM FST Postgraduate Colloquium
CountryMalaysia
CitySelangor
Period12/7/1713/7/17

Fingerprint

porphyrins
antennas
synthesis
molecules
nuclear magnetic resonance
pyrroles
spectroscopy
condensation

Keywords

  • Light Harvesting Properties
  • Multiporphyrin arrays
  • Porphyrins

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Radzuan, N. H. M., Hassan, N. I., & Abu Bakar, M. (2018). Synthesis of borylated porphyrin and bromo-porphyrin as building blocks for light harvesting antenna molecule. In 2017 UKM FST Postgraduate Colloquium: Proceedings of the University Kebangsaan Malaysia, Faculty of Science and Technology 2017 Postgraduate Colloquium (Vol. 1940). [020098] American Institute of Physics Inc.. https://doi.org/10.1063/1.5028013

Synthesis of borylated porphyrin and bromo-porphyrin as building blocks for light harvesting antenna molecule. / Radzuan, Nuur Haziqah Mohd; Hassan, Nurul Izzaty; Abu Bakar, Muntaz.

2017 UKM FST Postgraduate Colloquium: Proceedings of the University Kebangsaan Malaysia, Faculty of Science and Technology 2017 Postgraduate Colloquium. Vol. 1940 American Institute of Physics Inc., 2018. 020098.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Radzuan, NHM, Hassan, NI & Abu Bakar, M 2018, Synthesis of borylated porphyrin and bromo-porphyrin as building blocks for light harvesting antenna molecule. in 2017 UKM FST Postgraduate Colloquium: Proceedings of the University Kebangsaan Malaysia, Faculty of Science and Technology 2017 Postgraduate Colloquium. vol. 1940, 020098, American Institute of Physics Inc., 2017 UKM FST Postgraduate Colloquium, Selangor, Malaysia, 12/7/17. https://doi.org/10.1063/1.5028013
Radzuan NHM, Hassan NI, Abu Bakar M. Synthesis of borylated porphyrin and bromo-porphyrin as building blocks for light harvesting antenna molecule. In 2017 UKM FST Postgraduate Colloquium: Proceedings of the University Kebangsaan Malaysia, Faculty of Science and Technology 2017 Postgraduate Colloquium. Vol. 1940. American Institute of Physics Inc. 2018. 020098 https://doi.org/10.1063/1.5028013
Radzuan, Nuur Haziqah Mohd ; Hassan, Nurul Izzaty ; Abu Bakar, Muntaz. / Synthesis of borylated porphyrin and bromo-porphyrin as building blocks for light harvesting antenna molecule. 2017 UKM FST Postgraduate Colloquium: Proceedings of the University Kebangsaan Malaysia, Faculty of Science and Technology 2017 Postgraduate Colloquium. Vol. 1940 American Institute of Physics Inc., 2018.
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abstract = "The building blocks for synthesis of light harvesting antenna which are 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane)-10,20-diphenylporphyrin, 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane)-10,20-dihexylporphyrin and 5,10,15,20-Tetra-(bromophenyl)porphyrin were synthesized. Borylated porphyrin was synthesized by Suzuki coupling reaction between A2BC bromo-porphyrin and pinacolborane. Whereas 5,10,15,20-Tetra-(bromophenyl) porphyrin was synthesized by Lindsey condensation reaction between pyrrole and 4-bromobenzaldehyde. 1H-NMR, 13C-NMR spectroscopy and UV-visible spectroscopy confirmed the successful formation of all compounds.",
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