Synthesis and structural characterization of new dithiocarbamate complexes from Sb(III) and Bi(III)

Nur Amirah Jamaluddin, Ibrahim Baba

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    5 Citations (Scopus)

    Abstract

    Twenty new antimony and bismuth dithiocarbamate complexes which employed ten different type of amines have been successfully synthesized. The synthesized complexes with metal to dithiocarbamate ratio at 1:3. Elemental analysis of the complexes gave the general formula of MCl[S2CNR'R"]2 where M = Sb(III), Bi(III); R' = methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, benzyl; R" = ethanol, methyl, ethyl, propyl, isopropyl, cyclohexyl, benzyl. The complexes were analysed by IR and NMR spectroscopy. The crystal structure of five-coordinated antimony (III) complex have been determined by X-ray single crystal diffraction. Single crystal X-ray diffraction studies on SbCl[S2CN(C4H9)(C2H 5)]2 adopted a triclinic system with a space group P1 with a = 10.0141(8) Å, b = 10.1394(7) Å, c = 11.8665(9) Å, α = 67.960°, β =87.616°, γ = 80.172°.

    Original languageEnglish
    Title of host publicationAIP Conference Proceedings
    Pages789-794
    Number of pages6
    Volume1571
    DOIs
    Publication statusPublished - 2013
    Event2013 UKM Faculty of Science and Technology Post-Graduate Colloquium - Selangor
    Duration: 3 Jul 20134 Jul 2013

    Other

    Other2013 UKM Faculty of Science and Technology Post-Graduate Colloquium
    CitySelangor
    Period3/7/134/7/13

    Fingerprint

    antimony
    single crystals
    synthesis
    diffraction
    bismuth
    amines
    ethyl alcohol
    x rays
    nuclear magnetic resonance
    crystal structure
    metals
    spectroscopy

    Keywords

    • Bismuth(III)
    • Dithiocarbamate
    • Stibium(III)

    ASJC Scopus subject areas

    • Physics and Astronomy(all)

    Cite this

    Jamaluddin, N. A., & Baba, I. (2013). Synthesis and structural characterization of new dithiocarbamate complexes from Sb(III) and Bi(III). In AIP Conference Proceedings (Vol. 1571, pp. 789-794) https://doi.org/10.1063/1.4858751

    Synthesis and structural characterization of new dithiocarbamate complexes from Sb(III) and Bi(III). / Jamaluddin, Nur Amirah; Baba, Ibrahim.

    AIP Conference Proceedings. Vol. 1571 2013. p. 789-794.

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Jamaluddin, NA & Baba, I 2013, Synthesis and structural characterization of new dithiocarbamate complexes from Sb(III) and Bi(III). in AIP Conference Proceedings. vol. 1571, pp. 789-794, 2013 UKM Faculty of Science and Technology Post-Graduate Colloquium, Selangor, 3/7/13. https://doi.org/10.1063/1.4858751
    Jamaluddin, Nur Amirah ; Baba, Ibrahim. / Synthesis and structural characterization of new dithiocarbamate complexes from Sb(III) and Bi(III). AIP Conference Proceedings. Vol. 1571 2013. pp. 789-794
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