Abstract
Acetophenone thiosemicarbazone (APTSC) was synthesized. Solubility of APTSC was determined in ethanol and methanol at different temperatures. Single crystals were grown from ethanol by slow evaporation at room temperature. The grown crystal was subjected to FTIR, Laser-Raman and 1H NMR spectral analyses to confirm the synthesized compound. Thermal properties were investigated by thermogravimetric and differential thermal analyses. High-resolution X-ray diffractometry (HRXRD) was employed to evaluate the perfection of the grown crystal. The range and percentage of optical transmission was ascertained by recording UV-vis-NIR spectrum. The third order nonlinear optical parameters (nonlinear refractive index and nonlinear absorption coefficient) were derived by the Z-scan technique.
| Original language | English |
|---|---|
| Pages (from-to) | 369-375 |
| Number of pages | 7 |
| Journal | Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy |
| Volume | 76 |
| Issue number | 3-4 |
| DOIs | |
| Publication status | Published - Aug 2010 |
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Keywords
- Nonlinear optical materials
- Nuclear magnetic resonance
- Organic compounds
- Powder diffraction
- Solution growth
ASJC Scopus subject areas
- Instrumentation
- Atomic and Molecular Physics, and Optics
- Analytical Chemistry
- Spectroscopy
Cite this
Synthesis and spectral characterization of acetophenone thiosemicarbazone-A nonlinear optical material. / Santhakumari, R.; Ramamurthi, K.; Vasuki, G.; Mohd. Yamin, Bohari; Bhagavannarayana, G.
In: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, Vol. 76, No. 3-4, 08.2010, p. 369-375.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and spectral characterization of acetophenone thiosemicarbazone-A nonlinear optical material
AU - Santhakumari, R.
AU - Ramamurthi, K.
AU - Vasuki, G.
AU - Mohd. Yamin, Bohari
AU - Bhagavannarayana, G.
PY - 2010/8
Y1 - 2010/8
N2 - Acetophenone thiosemicarbazone (APTSC) was synthesized. Solubility of APTSC was determined in ethanol and methanol at different temperatures. Single crystals were grown from ethanol by slow evaporation at room temperature. The grown crystal was subjected to FTIR, Laser-Raman and 1H NMR spectral analyses to confirm the synthesized compound. Thermal properties were investigated by thermogravimetric and differential thermal analyses. High-resolution X-ray diffractometry (HRXRD) was employed to evaluate the perfection of the grown crystal. The range and percentage of optical transmission was ascertained by recording UV-vis-NIR spectrum. The third order nonlinear optical parameters (nonlinear refractive index and nonlinear absorption coefficient) were derived by the Z-scan technique.
AB - Acetophenone thiosemicarbazone (APTSC) was synthesized. Solubility of APTSC was determined in ethanol and methanol at different temperatures. Single crystals were grown from ethanol by slow evaporation at room temperature. The grown crystal was subjected to FTIR, Laser-Raman and 1H NMR spectral analyses to confirm the synthesized compound. Thermal properties were investigated by thermogravimetric and differential thermal analyses. High-resolution X-ray diffractometry (HRXRD) was employed to evaluate the perfection of the grown crystal. The range and percentage of optical transmission was ascertained by recording UV-vis-NIR spectrum. The third order nonlinear optical parameters (nonlinear refractive index and nonlinear absorption coefficient) were derived by the Z-scan technique.
KW - Nonlinear optical materials
KW - Nuclear magnetic resonance
KW - Organic compounds
KW - Powder diffraction
KW - Solution growth
UR - http://www.scopus.com/inward/record.url?scp=77953288163&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77953288163&partnerID=8YFLogxK
U2 - 10.1016/j.saa.2010.03.030
DO - 10.1016/j.saa.2010.03.030
M3 - Article
VL - 76
SP - 369
EP - 375
JO - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
JF - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
SN - 1386-1425
IS - 3-4
ER -