Synthesis and oxidation of (E)-1,2-diphenyl-2-(arylimino) ethanol derivatives

Zakaria H. Aiube, Sabah T. Najiam, Abdul Amir H. Kadhum

Research output: Contribution to journalArticle

Abstract

The compounds (E)-1,2-diphenyl-2-(phenylimino)ethanol, (E)-1,2-diphenyl-2- (p-tolylimino)ethanol, and (E)-2-((4-chlorophenyl)imino)-1,2-diphenylethanol) were synthesized by reaction of a p-substituted aniline with benzoin then oxidized with chromium trioxide-triethylamine in chloroform to give (E)-1,2-diphenyl-2-(phenylimino)ethanone, (E)-1,2-diphenyl-2-(p-tolylimino) ethanone, and (E)-2-((4-chlorophenyl)imino)-1,2-diphenylethanone in very high yield. The products were characterized by IR and NMR spectral analysis.

Original languageEnglish
Pages (from-to)2351-2355
Number of pages5
JournalResearch on Chemical Intermediates
Volume39
Issue number6
DOIs
Publication statusPublished - Jul 2013

Fingerprint

Ethanol
Derivatives
Oxidation
Benzoin
Chloroform
Spectrum analysis
Nuclear magnetic resonance
diphenyl

Keywords

  • Benzil
  • Benzoin Schiff base
  • Chromium trioxide
  • p,x-Substituted aniline

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Synthesis and oxidation of (E)-1,2-diphenyl-2-(arylimino) ethanol derivatives. / Aiube, Zakaria H.; Najiam, Sabah T.; Kadhum, Abdul Amir H.

In: Research on Chemical Intermediates, Vol. 39, No. 6, 07.2013, p. 2351-2355.

Research output: Contribution to journalArticle

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