Synthesis and optical properties of dipolar thiazole derivatives incorporating nitro and amino substituents

Noor Aisyah Ahmad Shah, Nur Farahin Pairan, Noor Azilah Mohd Kasim, Bohari Mohd. Yamin

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

We report the synthesis of two dipolar thiazole derivatives functionalized with nitro group as electron acceptor and amino group as electron donor, in order to study their optical properties in the UV-vis range. Their structures were verified by 1H NMR, 13C NMR, HRMS and FT-IR. The resulted thiazole derivatives have good thermal stability with decomposition temperature, Td of 320.20°C and 284°C for compounds 1 and 2 respectively. The absorbance bands of compound 2 in the UV-vis range are more red-shifted than that of compound 1 which made compound 2 could have high potential as a great organic NLO material.

Original languageEnglish
Title of host publicationApplied Engineering, Materials and Mechanics II
EditorsJong Wan Hu
PublisherTrans Tech Publications Ltd
Pages157-161
Number of pages5
ISBN (Print)9783035713374
DOIs
Publication statusPublished - 1 Jan 2018
Event3rd International Conference on Applied Engineering, Materials and Mechanics, ICAEMM 2018 - Okinawa Island, Japan
Duration: 20 Apr 201822 Apr 2018

Publication series

NameKey Engineering Materials
Volume773 KEM
ISSN (Print)1013-9826

Other

Other3rd International Conference on Applied Engineering, Materials and Mechanics, ICAEMM 2018
CountryJapan
CityOkinawa Island
Period20/4/1822/4/18

Fingerprint

Thiazoles
Optical properties
Nuclear magnetic resonance
Derivatives
Electrons
Thermodynamic stability
Decomposition
Temperature

Keywords

  • Dipolar thiazole
  • NLO
  • Push-pull
  • Thermal stability
  • Thiazole derivative

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Shah, N. A. A., Pairan, N. F., Kasim, N. A. M., & Mohd. Yamin, B. (2018). Synthesis and optical properties of dipolar thiazole derivatives incorporating nitro and amino substituents. In J. W. Hu (Ed.), Applied Engineering, Materials and Mechanics II (pp. 157-161). (Key Engineering Materials; Vol. 773 KEM). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/KEM.773.157

Synthesis and optical properties of dipolar thiazole derivatives incorporating nitro and amino substituents. / Shah, Noor Aisyah Ahmad; Pairan, Nur Farahin; Kasim, Noor Azilah Mohd; Mohd. Yamin, Bohari.

Applied Engineering, Materials and Mechanics II. ed. / Jong Wan Hu. Trans Tech Publications Ltd, 2018. p. 157-161 (Key Engineering Materials; Vol. 773 KEM).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Shah, NAA, Pairan, NF, Kasim, NAM & Mohd. Yamin, B 2018, Synthesis and optical properties of dipolar thiazole derivatives incorporating nitro and amino substituents. in JW Hu (ed.), Applied Engineering, Materials and Mechanics II. Key Engineering Materials, vol. 773 KEM, Trans Tech Publications Ltd, pp. 157-161, 3rd International Conference on Applied Engineering, Materials and Mechanics, ICAEMM 2018, Okinawa Island, Japan, 20/4/18. https://doi.org/10.4028/www.scientific.net/KEM.773.157
Shah NAA, Pairan NF, Kasim NAM, Mohd. Yamin B. Synthesis and optical properties of dipolar thiazole derivatives incorporating nitro and amino substituents. In Hu JW, editor, Applied Engineering, Materials and Mechanics II. Trans Tech Publications Ltd. 2018. p. 157-161. (Key Engineering Materials). https://doi.org/10.4028/www.scientific.net/KEM.773.157
Shah, Noor Aisyah Ahmad ; Pairan, Nur Farahin ; Kasim, Noor Azilah Mohd ; Mohd. Yamin, Bohari. / Synthesis and optical properties of dipolar thiazole derivatives incorporating nitro and amino substituents. Applied Engineering, Materials and Mechanics II. editor / Jong Wan Hu. Trans Tech Publications Ltd, 2018. pp. 157-161 (Key Engineering Materials).
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