Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic

Nurul Atikah Bt Safiin, Mohd. Ambar Yarmo, Bohari Mohd. Yamin

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A two dimensional metal organic framework containing cerium sufate layers and ethylenediaminium between layers was obtained by refluxing the mixture of cerium sulphate and 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7, 14-diene bromide. The complex was characterized by infrared spectroscopy and microelemental analysis. X-ray study showed that the complex adopts eleven coordination environments about the central atom. Thermogravimetric study showed the removal of water molecules at about 70 °C followed by a gradual mass loss until the whole structure collapsed at about 400 °C.

Original languageEnglish
Title of host publicationAIP Conference Proceedings
Pages857-865
Number of pages9
Volume1571
DOIs
Publication statusPublished - 2013
Event2013 UKM Faculty of Science and Technology Post-Graduate Colloquium - Selangor
Duration: 3 Jul 20134 Jul 2013

Other

Other2013 UKM Faculty of Science and Technology Post-Graduate Colloquium
CitySelangor
Period3/7/134/7/13

Fingerprint

cerium
dienes
synthesis
metals
bromides
sulfates
infrared spectroscopy
water
atoms
molecules
x rays

Keywords

  • Lanthanide
  • Metal organic framework
  • Thermal
  • X-ray crystallography

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic. / Bt Safiin, Nurul Atikah; Yarmo, Mohd. Ambar; Mohd. Yamin, Bohari.

AIP Conference Proceedings. Vol. 1571 2013. p. 857-865.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Bt Safiin, NA, Yarmo, MA & Mohd. Yamin, B 2013, Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic. in AIP Conference Proceedings. vol. 1571, pp. 857-865, 2013 UKM Faculty of Science and Technology Post-Graduate Colloquium, Selangor, 3/7/13. https://doi.org/10.1063/1.4858762
Bt Safiin, Nurul Atikah ; Yarmo, Mohd. Ambar ; Mohd. Yamin, Bohari. / Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic. AIP Conference Proceedings. Vol. 1571 2013. pp. 857-865
@inproceedings{538af4073513493486f10b5c6ddd0f24,
title = "Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic",
abstract = "A two dimensional metal organic framework containing cerium sufate layers and ethylenediaminium between layers was obtained by refluxing the mixture of cerium sulphate and 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7, 14-diene bromide. The complex was characterized by infrared spectroscopy and microelemental analysis. X-ray study showed that the complex adopts eleven coordination environments about the central atom. Thermogravimetric study showed the removal of water molecules at about 70 °C followed by a gradual mass loss until the whole structure collapsed at about 400 °C.",
keywords = "Lanthanide, Metal organic framework, Thermal, X-ray crystallography",
author = "{Bt Safiin}, {Nurul Atikah} and Yarmo, {Mohd. Ambar} and {Mohd. Yamin}, Bohari",
year = "2013",
doi = "10.1063/1.4858762",
language = "English",
isbn = "9780735411999",
volume = "1571",
pages = "857--865",
booktitle = "AIP Conference Proceedings",

}

TY - GEN

T1 - Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic

AU - Bt Safiin, Nurul Atikah

AU - Yarmo, Mohd. Ambar

AU - Mohd. Yamin, Bohari

PY - 2013

Y1 - 2013

N2 - A two dimensional metal organic framework containing cerium sufate layers and ethylenediaminium between layers was obtained by refluxing the mixture of cerium sulphate and 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7, 14-diene bromide. The complex was characterized by infrared spectroscopy and microelemental analysis. X-ray study showed that the complex adopts eleven coordination environments about the central atom. Thermogravimetric study showed the removal of water molecules at about 70 °C followed by a gradual mass loss until the whole structure collapsed at about 400 °C.

AB - A two dimensional metal organic framework containing cerium sufate layers and ethylenediaminium between layers was obtained by refluxing the mixture of cerium sulphate and 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7, 14-diene bromide. The complex was characterized by infrared spectroscopy and microelemental analysis. X-ray study showed that the complex adopts eleven coordination environments about the central atom. Thermogravimetric study showed the removal of water molecules at about 70 °C followed by a gradual mass loss until the whole structure collapsed at about 400 °C.

KW - Lanthanide

KW - Metal organic framework

KW - Thermal

KW - X-ray crystallography

UR - http://www.scopus.com/inward/record.url?scp=84897753429&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84897753429&partnerID=8YFLogxK

U2 - 10.1063/1.4858762

DO - 10.1063/1.4858762

M3 - Conference contribution

SN - 9780735411999

VL - 1571

SP - 857

EP - 865

BT - AIP Conference Proceedings

ER -