Synthesis and characterization of poly (benzyl trimethyl ammonium chloride) ionic polymer

Manjusha Elizabeth Mathew, Ishak Ahmad, Sabu Thomas, Rusli Daik, Mohammad Kassim

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Poly vinyl benzyl chloride (PVBC) was synthesized by free radical polymerization of 4-vinyl benzyl chloride (VBC) using benzoyl peroxide initiator at 80°C. Amine functionalised polymer prepared by treatment of PVBC with trimethyl amine in different solvents such as water, ethanol, tetra hydro furan(THF) and dimethyl formamide(DMF). The polymers characterized structurally by nuclear magnetic resonance and infrared spectroscopic techniques. The thermal decomposition of the polymer is studied by Thermo Gravimetric Analysis(TGA) and found that the polymer has stability up to 230°C. The nitrogen content of the aminated polymer determined by elemental analysis. The nitrogen content obtained from tetra hydro furan and dimethyl formamide solvents are 20.1% and 19.9% respectively.

Original languageEnglish
Title of host publication2017 UKM FST Postgraduate Colloquium
Subtitle of host publicationProceedings of the University Kebangsaan Malaysia, Faculty of Science and Technology 2017 Postgraduate Colloquium
PublisherAmerican Institute of Physics Inc.
Volume1940
ISBN (Electronic)9780735416321
DOIs
Publication statusPublished - 4 Apr 2018
Event2017 UKM FST Postgraduate Colloquium - Selangor, Malaysia
Duration: 12 Jul 201713 Jul 2017

Other

Other2017 UKM FST Postgraduate Colloquium
CountryMalaysia
CitySelangor
Period12/7/1713/7/17

Fingerprint

ammonium chlorides
polymers
synthesis
furans
chlorides
amines
nitrogen
peroxides
initiators
free radicals
thermal decomposition
ethyl alcohol
polymerization
nuclear magnetic resonance
water

Keywords

  • aminated polyvinyl benzyl chloride.
  • Poly (vinyl benzyl chloride)
  • trimethyl amine

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Mathew, M. E., Ahmad, I., Thomas, S., Daik, R., & Kassim, M. (2018). Synthesis and characterization of poly (benzyl trimethyl ammonium chloride) ionic polymer. In 2017 UKM FST Postgraduate Colloquium: Proceedings of the University Kebangsaan Malaysia, Faculty of Science and Technology 2017 Postgraduate Colloquium (Vol. 1940). [020108] American Institute of Physics Inc.. https://doi.org/10.1063/1.5028023

Synthesis and characterization of poly (benzyl trimethyl ammonium chloride) ionic polymer. / Mathew, Manjusha Elizabeth; Ahmad, Ishak; Thomas, Sabu; Daik, Rusli; Kassim, Mohammad.

2017 UKM FST Postgraduate Colloquium: Proceedings of the University Kebangsaan Malaysia, Faculty of Science and Technology 2017 Postgraduate Colloquium. Vol. 1940 American Institute of Physics Inc., 2018. 020108.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Mathew, ME, Ahmad, I, Thomas, S, Daik, R & Kassim, M 2018, Synthesis and characterization of poly (benzyl trimethyl ammonium chloride) ionic polymer. in 2017 UKM FST Postgraduate Colloquium: Proceedings of the University Kebangsaan Malaysia, Faculty of Science and Technology 2017 Postgraduate Colloquium. vol. 1940, 020108, American Institute of Physics Inc., 2017 UKM FST Postgraduate Colloquium, Selangor, Malaysia, 12/7/17. https://doi.org/10.1063/1.5028023
Mathew ME, Ahmad I, Thomas S, Daik R, Kassim M. Synthesis and characterization of poly (benzyl trimethyl ammonium chloride) ionic polymer. In 2017 UKM FST Postgraduate Colloquium: Proceedings of the University Kebangsaan Malaysia, Faculty of Science and Technology 2017 Postgraduate Colloquium. Vol. 1940. American Institute of Physics Inc. 2018. 020108 https://doi.org/10.1063/1.5028023
Mathew, Manjusha Elizabeth ; Ahmad, Ishak ; Thomas, Sabu ; Daik, Rusli ; Kassim, Mohammad. / Synthesis and characterization of poly (benzyl trimethyl ammonium chloride) ionic polymer. 2017 UKM FST Postgraduate Colloquium: Proceedings of the University Kebangsaan Malaysia, Faculty of Science and Technology 2017 Postgraduate Colloquium. Vol. 1940 American Institute of Physics Inc., 2018.
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abstract = "Poly vinyl benzyl chloride (PVBC) was synthesized by free radical polymerization of 4-vinyl benzyl chloride (VBC) using benzoyl peroxide initiator at 80°C. Amine functionalised polymer prepared by treatment of PVBC with trimethyl amine in different solvents such as water, ethanol, tetra hydro furan(THF) and dimethyl formamide(DMF). The polymers characterized structurally by nuclear magnetic resonance and infrared spectroscopic techniques. The thermal decomposition of the polymer is studied by Thermo Gravimetric Analysis(TGA) and found that the polymer has stability up to 230°C. The nitrogen content of the aminated polymer determined by elemental analysis. The nitrogen content obtained from tetra hydro furan and dimethyl formamide solvents are 20.1{\%} and 19.9{\%} respectively.",
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