Synthesis and characterization of N,N'-bis[4-[1-(2-hidroxyethoxy)]salicylidine]-phenyldiamine-nickel(II)] complex

Roshatiara Binti Shamsuddin, Nurul Huda Abd Karim

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

N,N'-bis[4-[1-(2-hidroxyethoxy)]salicylidine]-phenyldiamine-nickel(II) complex has been synthesized by treating N,N'-bis-4-(hydroxysalicylidene)-phenylenediamine-nickel(II) complex with 2-chloroethanol and nickel(II) acetate tetrahydrate in ethanol solvent. The resulting complex formed was characterized using standard spectroscopic and structural techniques which includes 1H, 13C, COSY and HMQC NMR spectroscopy, FTIR spectroscopy and ESI-MS spectrometry. The 1H NMR spectrum displayed all the expected signals with right integration and multiplicity. The formation of Schiff base can be seen at 8.54 ppm for the formation of diimine and the disappearance of aldehyde peak at 9.88 ppm corresponding to the starting material confirms the full conversion. The presence of resonance peak at 3.76 ppm and 4.00 ppm corresponding to the ethyl group of the hydroxyl side chain also confirm the formation of the complex. The FTIR spectrum of the complex confirmed the expected C=N band at 1577 cm-1 and C-H for sp3 stretching band at 2878 cm-1. The formation of the new complex was also confirmed by ESI(+)-MS spectrometry, which showed the molecular peak with adduct ions at [M+K]+=531 a.m.u and [M+Na]+=515 a.m.u.

Original languageEnglish
Title of host publication2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium
PublisherAmerican Institute of Physics Inc.
Volume1784
ISBN (Electronic)9780735414464
DOIs
Publication statusPublished - 17 Nov 2016
Event2016 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2016 - Selangor, Malaysia
Duration: 13 Apr 201614 Apr 2016

Other

Other2016 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2016
CountryMalaysia
CitySelangor
Period13/4/1614/4/16

Fingerprint

nickel
synthesis
spectroscopy
nuclear magnetic resonance
aldehydes
imines
adducts
acetates
ethyl alcohol
ions

Keywords

  • Complex
  • ligand
  • metal

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Shamsuddin, R. B., & Abd Karim, N. H. (2016). Synthesis and characterization of N,N'-bis[4-[1-(2-hidroxyethoxy)]salicylidine]-phenyldiamine-nickel(II)] complex. In 2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium (Vol. 1784). [030007] American Institute of Physics Inc.. https://doi.org/10.1063/1.4966745

Synthesis and characterization of N,N'-bis[4-[1-(2-hidroxyethoxy)]salicylidine]-phenyldiamine-nickel(II)] complex. / Shamsuddin, Roshatiara Binti; Abd Karim, Nurul Huda.

2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium. Vol. 1784 American Institute of Physics Inc., 2016. 030007.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Shamsuddin, RB & Abd Karim, NH 2016, Synthesis and characterization of N,N'-bis[4-[1-(2-hidroxyethoxy)]salicylidine]-phenyldiamine-nickel(II)] complex. in 2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium. vol. 1784, 030007, American Institute of Physics Inc., 2016 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2016, Selangor, Malaysia, 13/4/16. https://doi.org/10.1063/1.4966745
Shamsuddin RB, Abd Karim NH. Synthesis and characterization of N,N'-bis[4-[1-(2-hidroxyethoxy)]salicylidine]-phenyldiamine-nickel(II)] complex. In 2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium. Vol. 1784. American Institute of Physics Inc. 2016. 030007 https://doi.org/10.1063/1.4966745
Shamsuddin, Roshatiara Binti ; Abd Karim, Nurul Huda. / Synthesis and characterization of N,N'-bis[4-[1-(2-hidroxyethoxy)]salicylidine]-phenyldiamine-nickel(II)] complex. 2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium. Vol. 1784 American Institute of Physics Inc., 2016.
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