Synthesis and characterization of dimethyltin(IV) complex with 2-methylpyridylbenzhydrazone (AcPyBzh): Crystal structure of [Me2SnCl (AcPyBzh)]

M. A. Affan, Fasihuddin B. Ahmad, Ramli B. Hitam, Mustafa B. Shamsuddin, Bohari Mohd. Yamin

Research output: Contribution to journalArticle

Abstract

The reaction of dimethyltin(IV) dihalide with 2-methylpyridylbenzhydrazone (AcPyBzh) afforded the complex compound [Me2SnCl(AcPyBzh)]. The complex was characterized by IR, 1H and 13C-{ 1H} NMR spectroscopic techniques and elemental analyses. The crystal structure of [Me2SnCL(AcPyBzh)] has been determined. The AcPyBzh anion in this complex acts as a monobasic NNO bidentate ligand, the tin(IV) lying in an elongated distrorted trigonal bipyramidal environment where the azomethine nitrogen and amidate oxygen, together with the two-methyl carbons, are in the equatorial plane, whereas the chloride is the apical ligand. The crystal is monoclinic, space group P2(I)/n, with a = 12.0945 (3), b = 7.5167 (2), c = 19.9795 (4) Å, α = 90°, β= 105.85°, γ = 90°.

Original languageEnglish
Pages (from-to)381-385
Number of pages5
JournalPakistan Journal of Scientific and Industrial Research
Volume48
Issue number6
Publication statusPublished - Nov 2005

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Crystal structure
Ligands
Tin
Negative ions
Nuclear magnetic resonance
Nitrogen
Crystals
Carbon
Oxygen

Keywords

  • 2-methylpyridylbenzhydrazone ligand
  • Crystal structure
  • Dimethyltin(IV) complex
  • Organotin(IV) complexes

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Synthesis and characterization of dimethyltin(IV) complex with 2-methylpyridylbenzhydrazone (AcPyBzh) : Crystal structure of [Me2SnCl (AcPyBzh)]. / Affan, M. A.; Ahmad, Fasihuddin B.; Hitam, Ramli B.; Shamsuddin, Mustafa B.; Mohd. Yamin, Bohari.

In: Pakistan Journal of Scientific and Industrial Research, Vol. 48, No. 6, 11.2005, p. 381-385.

Research output: Contribution to journalArticle

Affan, M. A. ; Ahmad, Fasihuddin B. ; Hitam, Ramli B. ; Shamsuddin, Mustafa B. ; Mohd. Yamin, Bohari. / Synthesis and characterization of dimethyltin(IV) complex with 2-methylpyridylbenzhydrazone (AcPyBzh) : Crystal structure of [Me2SnCl (AcPyBzh)]. In: Pakistan Journal of Scientific and Industrial Research. 2005 ; Vol. 48, No. 6. pp. 381-385.
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T2 - Crystal structure of [Me2SnCl (AcPyBzh)]

AU - Affan, M. A.

AU - Ahmad, Fasihuddin B.

AU - Hitam, Ramli B.

AU - Shamsuddin, Mustafa B.

AU - Mohd. Yamin, Bohari

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N2 - The reaction of dimethyltin(IV) dihalide with 2-methylpyridylbenzhydrazone (AcPyBzh) afforded the complex compound [Me2SnCl(AcPyBzh)]. The complex was characterized by IR, 1H and 13C-{ 1H} NMR spectroscopic techniques and elemental analyses. The crystal structure of [Me2SnCL(AcPyBzh)] has been determined. The AcPyBzh anion in this complex acts as a monobasic NNO bidentate ligand, the tin(IV) lying in an elongated distrorted trigonal bipyramidal environment where the azomethine nitrogen and amidate oxygen, together with the two-methyl carbons, are in the equatorial plane, whereas the chloride is the apical ligand. The crystal is monoclinic, space group P2(I)/n, with a = 12.0945 (3), b = 7.5167 (2), c = 19.9795 (4) Å, α = 90°, β= 105.85°, γ = 90°.

AB - The reaction of dimethyltin(IV) dihalide with 2-methylpyridylbenzhydrazone (AcPyBzh) afforded the complex compound [Me2SnCl(AcPyBzh)]. The complex was characterized by IR, 1H and 13C-{ 1H} NMR spectroscopic techniques and elemental analyses. The crystal structure of [Me2SnCL(AcPyBzh)] has been determined. The AcPyBzh anion in this complex acts as a monobasic NNO bidentate ligand, the tin(IV) lying in an elongated distrorted trigonal bipyramidal environment where the azomethine nitrogen and amidate oxygen, together with the two-methyl carbons, are in the equatorial plane, whereas the chloride is the apical ligand. The crystal is monoclinic, space group P2(I)/n, with a = 12.0945 (3), b = 7.5167 (2), c = 19.9795 (4) Å, α = 90°, β= 105.85°, γ = 90°.

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KW - Organotin(IV) complexes

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