Synthesis and characterisation of organotin(IV) nethyl- N-phenyldithiocarbamate compounds and the crystal structures of dibutyl- And triphenyltin(IV) nethyl- N-phenyldithiocarbamate

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Abstract

A new series of organotin(IV) N-ethyl-Nphenyldithiocarbamate compounds has been synthesised between the reaction of N-ethylaniline amine with organotin(IV) chloride using in situ method. All compounds were characterised using elemental analysis, FT-IR and NMR spectroscopy. The crystal structures obtained were verified using Xray single crystal analysis. The elemental analysis data were in agreement with the general formula RnSn[S2CN(C2H5)(C6H5)]4-n (where R = Bu and Ph for n = 2; R = Ph for n = 3). The important infrared absorbance peaks and the chemical shifts of carbon in NCS2 group were detected in all compounds. Compound 1 was crystallised in monoclinic crystal system (C2/c space group) whereas compound 4 adopted triclinic crystal system (P-1 space group). The single crystal X-ray diffraction studies of both compounds showed that the dithiocarbamate ligands coordinate to central Sn(IV) atom in monodentate fashion.

Original languageEnglish
Pages (from-to)90-98
Number of pages9
JournalResearch Journal of Chemistry and Environment
Volume18
Issue number11
Publication statusPublished - 1 Nov 2014

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crystal structure
crystals
Crystal structure
Single crystals
crystal
Crystals
synthesis
Chemical shift
Chemical analysis
X-Ray Diffraction
Nuclear magnetic resonance spectroscopy
Amines
Chlorides
Infrared spectroscopy
Magnetic Resonance Spectroscopy
Carbon
Ligands
X-Rays
Infrared radiation
X ray diffraction

Keywords

  • Dibutyltin
  • Diphenyltin
  • Dithiocarbamate
  • Organotin
  • Triphenyltin

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Science(all)
  • Chemical Engineering(all)
  • Renewable Energy, Sustainability and the Environment
  • Biochemistry
  • Earth and Planetary Sciences(all)
  • Agricultural and Biological Sciences(all)

Cite this

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title = "Synthesis and characterisation of organotin(IV) nethyl- N-phenyldithiocarbamate compounds and the crystal structures of dibutyl- And triphenyltin(IV) nethyl- N-phenyldithiocarbamate",
abstract = "A new series of organotin(IV) N-ethyl-Nphenyldithiocarbamate compounds has been synthesised between the reaction of N-ethylaniline amine with organotin(IV) chloride using in situ method. All compounds were characterised using elemental analysis, FT-IR and NMR spectroscopy. The crystal structures obtained were verified using Xray single crystal analysis. The elemental analysis data were in agreement with the general formula RnSn[S2CN(C2H5)(C6H5)]4-n (where R = Bu and Ph for n = 2; R = Ph for n = 3). The important infrared absorbance peaks and the chemical shifts of carbon in NCS2 group were detected in all compounds. Compound 1 was crystallised in monoclinic crystal system (C2/c space group) whereas compound 4 adopted triclinic crystal system (P-1 space group). The single crystal X-ray diffraction studies of both compounds showed that the dithiocarbamate ligands coordinate to central Sn(IV) atom in monodentate fashion.",
keywords = "Dibutyltin, Diphenyltin, Dithiocarbamate, Organotin, Triphenyltin",
author = "{Nurul Farahana}, Kamaludin and Normah Awang",
year = "2014",
month = "11",
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language = "English",
volume = "18",
pages = "90--98",
journal = "Research Journal of Chemistry and Environment",
issn = "0972-0626",
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TY - JOUR

T1 - Synthesis and characterisation of organotin(IV) nethyl- N-phenyldithiocarbamate compounds and the crystal structures of dibutyl- And triphenyltin(IV) nethyl- N-phenyldithiocarbamate

AU - Nurul Farahana, Kamaludin

AU - Awang, Normah

PY - 2014/11/1

Y1 - 2014/11/1

N2 - A new series of organotin(IV) N-ethyl-Nphenyldithiocarbamate compounds has been synthesised between the reaction of N-ethylaniline amine with organotin(IV) chloride using in situ method. All compounds were characterised using elemental analysis, FT-IR and NMR spectroscopy. The crystal structures obtained were verified using Xray single crystal analysis. The elemental analysis data were in agreement with the general formula RnSn[S2CN(C2H5)(C6H5)]4-n (where R = Bu and Ph for n = 2; R = Ph for n = 3). The important infrared absorbance peaks and the chemical shifts of carbon in NCS2 group were detected in all compounds. Compound 1 was crystallised in monoclinic crystal system (C2/c space group) whereas compound 4 adopted triclinic crystal system (P-1 space group). The single crystal X-ray diffraction studies of both compounds showed that the dithiocarbamate ligands coordinate to central Sn(IV) atom in monodentate fashion.

AB - A new series of organotin(IV) N-ethyl-Nphenyldithiocarbamate compounds has been synthesised between the reaction of N-ethylaniline amine with organotin(IV) chloride using in situ method. All compounds were characterised using elemental analysis, FT-IR and NMR spectroscopy. The crystal structures obtained were verified using Xray single crystal analysis. The elemental analysis data were in agreement with the general formula RnSn[S2CN(C2H5)(C6H5)]4-n (where R = Bu and Ph for n = 2; R = Ph for n = 3). The important infrared absorbance peaks and the chemical shifts of carbon in NCS2 group were detected in all compounds. Compound 1 was crystallised in monoclinic crystal system (C2/c space group) whereas compound 4 adopted triclinic crystal system (P-1 space group). The single crystal X-ray diffraction studies of both compounds showed that the dithiocarbamate ligands coordinate to central Sn(IV) atom in monodentate fashion.

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KW - Triphenyltin

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