Synthesis and characterisation of new organotin (IV)(2-methoxyethyl)-methyldithiocarbamate complexes

Rapidah Mohamad, Normah Awang, Nurul Farahana Kamaludin

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Three new organotin(IV) dithiocarbamate complexes (complexes 1-3) employing (2-methoxyethyl)-methylamine as their secondary amine were successfully synthesised in situ. Elemental analysis of the complexes gave the general formula of RnSn[S2CN(C2H4OCH3)(CH3)]n-2 where R=C4H9(Bu)and C6H5(Ph)for n= 2; R= C6H11 (Cy) for n= 3. The complexes were analysed using FTIR and 1H, 13C, and 119Sn NMR. The important absorption peaks and chemical shift of NCS2 carbon were found in all the three complexes. 119Sn NMR suggested that tin atom in the complexes are coordinated by five and six coordination numbers.

Original languageEnglish
Pages (from-to)1920-1925
Number of pages6
JournalResearch Journal of Pharmaceutical, Biological and Chemical Sciences
Volume7
Issue number2
Publication statusPublished - 2016

Fingerprint

Tin
Fourier Transform Infrared Spectroscopy
Amines
Carbon
Nuclear magnetic resonance
Chemical shift
Atoms
Chemical analysis
methylamine
Carbon-13 Magnetic Resonance Spectroscopy
methyldithiocarbamate

Keywords

  • Complex
  • Elemental
  • Organotin

ASJC Scopus subject areas

  • Pharmacology, Toxicology and Pharmaceutics(all)
  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

Synthesis and characterisation of new organotin (IV)(2-methoxyethyl)-methyldithiocarbamate complexes. / Mohamad, Rapidah; Awang, Normah; Farahana Kamaludin, Nurul.

In: Research Journal of Pharmaceutical, Biological and Chemical Sciences, Vol. 7, No. 2, 2016, p. 1920-1925.

Research output: Contribution to journalArticle

@article{c2e2cf542d2d4bd2aa463608125409fd,
title = "Synthesis and characterisation of new organotin (IV)(2-methoxyethyl)-methyldithiocarbamate complexes",
abstract = "Three new organotin(IV) dithiocarbamate complexes (complexes 1-3) employing (2-methoxyethyl)-methylamine as their secondary amine were successfully synthesised in situ. Elemental analysis of the complexes gave the general formula of RnSn[S2CN(C2H4OCH3)(CH3)]n-2 where R=C4H9(Bu)and C6H5(Ph)for n= 2; R= C6H11 (Cy) for n= 3. The complexes were analysed using FTIR and 1H, 13C, and 119Sn NMR. The important absorption peaks and chemical shift of NCS2 carbon were found in all the three complexes. 119Sn NMR suggested that tin atom in the complexes are coordinated by five and six coordination numbers.",
keywords = "Complex, Elemental, Organotin",
author = "Rapidah Mohamad and Normah Awang and {Farahana Kamaludin}, Nurul",
year = "2016",
language = "English",
volume = "7",
pages = "1920--1925",
journal = "Research Journal of Pharmaceutical, Biological and Chemical Sciences",
issn = "0975-8585",
publisher = "RJPBCS",
number = "2",

}

TY - JOUR

T1 - Synthesis and characterisation of new organotin (IV)(2-methoxyethyl)-methyldithiocarbamate complexes

AU - Mohamad, Rapidah

AU - Awang, Normah

AU - Farahana Kamaludin, Nurul

PY - 2016

Y1 - 2016

N2 - Three new organotin(IV) dithiocarbamate complexes (complexes 1-3) employing (2-methoxyethyl)-methylamine as their secondary amine were successfully synthesised in situ. Elemental analysis of the complexes gave the general formula of RnSn[S2CN(C2H4OCH3)(CH3)]n-2 where R=C4H9(Bu)and C6H5(Ph)for n= 2; R= C6H11 (Cy) for n= 3. The complexes were analysed using FTIR and 1H, 13C, and 119Sn NMR. The important absorption peaks and chemical shift of NCS2 carbon were found in all the three complexes. 119Sn NMR suggested that tin atom in the complexes are coordinated by five and six coordination numbers.

AB - Three new organotin(IV) dithiocarbamate complexes (complexes 1-3) employing (2-methoxyethyl)-methylamine as their secondary amine were successfully synthesised in situ. Elemental analysis of the complexes gave the general formula of RnSn[S2CN(C2H4OCH3)(CH3)]n-2 where R=C4H9(Bu)and C6H5(Ph)for n= 2; R= C6H11 (Cy) for n= 3. The complexes were analysed using FTIR and 1H, 13C, and 119Sn NMR. The important absorption peaks and chemical shift of NCS2 carbon were found in all the three complexes. 119Sn NMR suggested that tin atom in the complexes are coordinated by five and six coordination numbers.

KW - Complex

KW - Elemental

KW - Organotin

UR - http://www.scopus.com/inward/record.url?scp=84962584325&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84962584325&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:84962584325

VL - 7

SP - 1920

EP - 1925

JO - Research Journal of Pharmaceutical, Biological and Chemical Sciences

JF - Research Journal of Pharmaceutical, Biological and Chemical Sciences

SN - 0975-8585

IS - 2

ER -