Synthesis and characterisation of diorganotin(IV) complexes of 3,4-dihydroxybenzaldehyde semicarbazone

Nasry Jassim Hussien, Yang Farina Abdul Aziz, Mohamad Jaber Al-Jeboori

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The diorganotin(IV) complexes of the type Me2SnL, Bu2SnL and Ph2SnL (L) with the anion of the semicarbazone ligand formed by condensation reaction of 3,4-dihydroxybenzaldehyde with semicarbazide were synthesized using 1:1 metal to ligand reactant ratios. The newly synthesized complexes were characterized using elemental analysis, infrared and nuclear magnetic resonance (1H, 13C,119Sn) spectroscopic techniques. Complex formation between the organotin(IV) moiety and the anion of 3,4-dihydroxybenzaldehysemicarbazone occurred with chelation at the o-dihydroxy positions. The complexes were proposed to have tetrahedral geometry.

Original languageEnglish
Title of host publication2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium
PublisherAmerican Institute of Physics Inc.
Volume1784
ISBN (Electronic)9780735414464
DOIs
Publication statusPublished - 17 Nov 2016
Event2016 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2016 - Selangor, Malaysia
Duration: 13 Apr 201614 Apr 2016

Other

Other2016 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2016
CountryMalaysia
CitySelangor
Period13/4/1614/4/16

Fingerprint

anions
ligands
chelation
synthesis
condensation
nuclear magnetic resonance
geometry
metals

Keywords

  • Catechol
  • Diorganotin
  • Schiff base
  • Semicarbazone
  • Synthesis

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Hussien, N. J., Abdul Aziz, Y. F., & Al-Jeboori, M. J. (2016). Synthesis and characterisation of diorganotin(IV) complexes of 3,4-dihydroxybenzaldehyde semicarbazone. In 2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium (Vol. 1784). [030006] American Institute of Physics Inc.. https://doi.org/10.1063/1.4966744

Synthesis and characterisation of diorganotin(IV) complexes of 3,4-dihydroxybenzaldehyde semicarbazone. / Hussien, Nasry Jassim; Abdul Aziz, Yang Farina; Al-Jeboori, Mohamad Jaber.

2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium. Vol. 1784 American Institute of Physics Inc., 2016. 030006.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Hussien, NJ, Abdul Aziz, YF & Al-Jeboori, MJ 2016, Synthesis and characterisation of diorganotin(IV) complexes of 3,4-dihydroxybenzaldehyde semicarbazone. in 2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium. vol. 1784, 030006, American Institute of Physics Inc., 2016 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2016, Selangor, Malaysia, 13/4/16. https://doi.org/10.1063/1.4966744
Hussien NJ, Abdul Aziz YF, Al-Jeboori MJ. Synthesis and characterisation of diorganotin(IV) complexes of 3,4-dihydroxybenzaldehyde semicarbazone. In 2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium. Vol. 1784. American Institute of Physics Inc. 2016. 030006 https://doi.org/10.1063/1.4966744
Hussien, Nasry Jassim ; Abdul Aziz, Yang Farina ; Al-Jeboori, Mohamad Jaber. / Synthesis and characterisation of diorganotin(IV) complexes of 3,4-dihydroxybenzaldehyde semicarbazone. 2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium. Vol. 1784 American Institute of Physics Inc., 2016.
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