Substituted esters of octadecanoic acid as potential biolubricants

Jumat Salimon, Nadia Salih

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Preparation and properties of seven diesters derivatives of 9, 10-dihydroxyoctadecanoic acid liquid as base stock were evaluated. The epoxidation of oleic acid followed by ring opening process in toluene with differnt saturated aliphatic fatty acids (octanoic, nonanoic, lauric, myristic, palmitic, stearic and behenic) and esterification process of the carbonyl group of oleic acid with butanol are discussed. The results showed that the most bulky ester groups in the mid chain with behenic acid exhibited favorable low-temperature performance. Compound 15 showed low pour point of -50°C, flash point of 187°C and moderate viscosity of 123 cp respectively.

Original languageEnglish
Pages (from-to)273-279
Number of pages7
JournalEuropean Journal of Scientific Research
Volume31
Issue number2
Publication statusPublished - 2009

Fingerprint

biolubricants
Oleic acid
Oleic Acid
stearic acid
ester
oleic acid
Esters
Fatty Acids
esters
pour point
Saturated fatty acids
Butanols
Group Processes
Epoxidation
Acids
Esterification
toluene
acids
acid
Toluene

Keywords

  • Biolubricants
  • Diesters
  • Epoxidation
  • Oleic acid

ASJC Scopus subject areas

  • General

Cite this

Substituted esters of octadecanoic acid as potential biolubricants. / Salimon, Jumat; Salih, Nadia.

In: European Journal of Scientific Research, Vol. 31, No. 2, 2009, p. 273-279.

Research output: Contribution to journalArticle

Salimon, Jumat ; Salih, Nadia. / Substituted esters of octadecanoic acid as potential biolubricants. In: European Journal of Scientific Research. 2009 ; Vol. 31, No. 2. pp. 273-279.
@article{ff1fe88bb7ef4f0dbf27cfba479c85e3,
title = "Substituted esters of octadecanoic acid as potential biolubricants",
abstract = "Preparation and properties of seven diesters derivatives of 9, 10-dihydroxyoctadecanoic acid liquid as base stock were evaluated. The epoxidation of oleic acid followed by ring opening process in toluene with differnt saturated aliphatic fatty acids (octanoic, nonanoic, lauric, myristic, palmitic, stearic and behenic) and esterification process of the carbonyl group of oleic acid with butanol are discussed. The results showed that the most bulky ester groups in the mid chain with behenic acid exhibited favorable low-temperature performance. Compound 15 showed low pour point of -50°C, flash point of 187°C and moderate viscosity of 123 cp respectively.",
keywords = "Biolubricants, Diesters, Epoxidation, Oleic acid",
author = "Jumat Salimon and Nadia Salih",
year = "2009",
language = "English",
volume = "31",
pages = "273--279",
journal = "European Journal of Scientific Research",
issn = "1450-202X",
publisher = "European Journals Inc.",
number = "2",

}

TY - JOUR

T1 - Substituted esters of octadecanoic acid as potential biolubricants

AU - Salimon, Jumat

AU - Salih, Nadia

PY - 2009

Y1 - 2009

N2 - Preparation and properties of seven diesters derivatives of 9, 10-dihydroxyoctadecanoic acid liquid as base stock were evaluated. The epoxidation of oleic acid followed by ring opening process in toluene with differnt saturated aliphatic fatty acids (octanoic, nonanoic, lauric, myristic, palmitic, stearic and behenic) and esterification process of the carbonyl group of oleic acid with butanol are discussed. The results showed that the most bulky ester groups in the mid chain with behenic acid exhibited favorable low-temperature performance. Compound 15 showed low pour point of -50°C, flash point of 187°C and moderate viscosity of 123 cp respectively.

AB - Preparation and properties of seven diesters derivatives of 9, 10-dihydroxyoctadecanoic acid liquid as base stock were evaluated. The epoxidation of oleic acid followed by ring opening process in toluene with differnt saturated aliphatic fatty acids (octanoic, nonanoic, lauric, myristic, palmitic, stearic and behenic) and esterification process of the carbonyl group of oleic acid with butanol are discussed. The results showed that the most bulky ester groups in the mid chain with behenic acid exhibited favorable low-temperature performance. Compound 15 showed low pour point of -50°C, flash point of 187°C and moderate viscosity of 123 cp respectively.

KW - Biolubricants

KW - Diesters

KW - Epoxidation

KW - Oleic acid

UR - http://www.scopus.com/inward/record.url?scp=67549095391&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67549095391&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:67549095391

VL - 31

SP - 273

EP - 279

JO - European Journal of Scientific Research

JF - European Journal of Scientific Research

SN - 1450-202X

IS - 2

ER -