Studies on the molar conductivity behavior of PMMA-co- MA electrolyte solution at different polymer concentrations

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Polymer is an important constituent of liquid polymer electrolyte along with salt and solvent. The limiting molar conductivity (A 0 ) and equilibrium constant (K eq ) for LiC10 4 in PMMA-co-MA solution was studied at 25.0 °C. Both A 0 and K eq were determined after Oswald's dilution law for a range of PMMA-co-MA concentrations (0.0010 - 0.0030 g cm -3 ). It was noticed that, as PMMA-co-MA concentration increased the A0 value showed a decreasing trend. However, this decreasing trend did not cause any significant improvement in total LiC10 4 dissociation for the electrolyte. This is supported by almost constant K eq values for the range of PMMA-co-MA concentration was at the same order of magnitude. The constant K eq with a decreasing A 0 might due to the formation of ions aggregation in the electrolyte.

Original languageEnglish
Title of host publication2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium
EditorsZahari Ibrahim, Haja Maideen Kader Maideen, Nazlina Ibrahim, Nurul Huda Abd Karim, Taufik Yusof, Fatimah Abdul Razak, Nurulkamal Maseran, Rozida Mohd Khalid, Noor Baa'yah Ibrahim, Hasidah Mohd. Sidek, Mohd Salmi Md Noorani, Norbert Simon
PublisherAmerican Institute of Physics Inc.
Pages295-301
Number of pages7
ISBN (Electronic)9780735412507
DOIs
Publication statusPublished - 1 Jan 2014
Event2014 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2014 - Selangor, Malaysia
Duration: 9 Apr 201411 Apr 2014

Publication series

NameAIP Conference Proceedings
Volume1614
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Other

Other2014 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2014
CountryMalaysia
CitySelangor
Period9/4/1411/4/14

Fingerprint

electrolytes
conductivity
polymers
trends
dilution
dissociation
salts
causes
liquids
ions

Keywords

  • Liquid polymer electrolyte
  • PPMA-co-MA

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Hanibah, H., Ahmad, A., & Hassan, N. H. (2014). Studies on the molar conductivity behavior of PMMA-co- MA electrolyte solution at different polymer concentrations. In Z. Ibrahim, H. M. K. Maideen, N. Ibrahim, N. H. A. Karim, T. Yusof, F. A. Razak, N. Maseran, R. M. Khalid, N. B. Ibrahim, H. M. Sidek, M. S. M. Noorani, ... N. Simon (Eds.), 2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium (pp. 295-301). (AIP Conference Proceedings; Vol. 1614). American Institute of Physics Inc.. https://doi.org/10.1063/1.4895211

Studies on the molar conductivity behavior of PMMA-co- MA electrolyte solution at different polymer concentrations. / Hanibah, Hussein; Ahmad, Azizan; Hassan, Nur Hasyareeda.

2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium. ed. / Zahari Ibrahim; Haja Maideen Kader Maideen; Nazlina Ibrahim; Nurul Huda Abd Karim; Taufik Yusof; Fatimah Abdul Razak; Nurulkamal Maseran; Rozida Mohd Khalid; Noor Baa'yah Ibrahim; Hasidah Mohd. Sidek; Mohd Salmi Md Noorani; Norbert Simon. American Institute of Physics Inc., 2014. p. 295-301 (AIP Conference Proceedings; Vol. 1614).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Hanibah, H, Ahmad, A & Hassan, NH 2014, Studies on the molar conductivity behavior of PMMA-co- MA electrolyte solution at different polymer concentrations. in Z Ibrahim, HMK Maideen, N Ibrahim, NHA Karim, T Yusof, FA Razak, N Maseran, RM Khalid, NB Ibrahim, HM Sidek, MSM Noorani & N Simon (eds), 2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium. AIP Conference Proceedings, vol. 1614, American Institute of Physics Inc., pp. 295-301, 2014 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2014, Selangor, Malaysia, 9/4/14. https://doi.org/10.1063/1.4895211
Hanibah H, Ahmad A, Hassan NH. Studies on the molar conductivity behavior of PMMA-co- MA electrolyte solution at different polymer concentrations. In Ibrahim Z, Maideen HMK, Ibrahim N, Karim NHA, Yusof T, Razak FA, Maseran N, Khalid RM, Ibrahim NB, Sidek HM, Noorani MSM, Simon N, editors, 2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium. American Institute of Physics Inc. 2014. p. 295-301. (AIP Conference Proceedings). https://doi.org/10.1063/1.4895211
Hanibah, Hussein ; Ahmad, Azizan ; Hassan, Nur Hasyareeda. / Studies on the molar conductivity behavior of PMMA-co- MA electrolyte solution at different polymer concentrations. 2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium. editor / Zahari Ibrahim ; Haja Maideen Kader Maideen ; Nazlina Ibrahim ; Nurul Huda Abd Karim ; Taufik Yusof ; Fatimah Abdul Razak ; Nurulkamal Maseran ; Rozida Mohd Khalid ; Noor Baa'yah Ibrahim ; Hasidah Mohd. Sidek ; Mohd Salmi Md Noorani ; Norbert Simon. American Institute of Physics Inc., 2014. pp. 295-301 (AIP Conference Proceedings).
@inproceedings{fa364ed17585450b82ae02b3f88f7d01,
title = "Studies on the molar conductivity behavior of PMMA-co- MA electrolyte solution at different polymer concentrations",
abstract = "Polymer is an important constituent of liquid polymer electrolyte along with salt and solvent. The limiting molar conductivity (A 0 ) and equilibrium constant (K eq ) for LiC10 4 in PMMA-co-MA solution was studied at 25.0 °C. Both A 0 and K eq were determined after Oswald's dilution law for a range of PMMA-co-MA concentrations (0.0010 - 0.0030 g cm -3 ). It was noticed that, as PMMA-co-MA concentration increased the A0 value showed a decreasing trend. However, this decreasing trend did not cause any significant improvement in total LiC10 4 dissociation for the electrolyte. This is supported by almost constant K eq values for the range of PMMA-co-MA concentration was at the same order of magnitude. The constant K eq with a decreasing A 0 might due to the formation of ions aggregation in the electrolyte.",
keywords = "Liquid polymer electrolyte, PPMA-co-MA",
author = "Hussein Hanibah and Azizan Ahmad and Hassan, {Nur Hasyareeda}",
year = "2014",
month = "1",
day = "1",
doi = "10.1063/1.4895211",
language = "English",
series = "AIP Conference Proceedings",
publisher = "American Institute of Physics Inc.",
pages = "295--301",
editor = "Zahari Ibrahim and Maideen, {Haja Maideen Kader} and Nazlina Ibrahim and Karim, {Nurul Huda Abd} and Taufik Yusof and Razak, {Fatimah Abdul} and Nurulkamal Maseran and Khalid, {Rozida Mohd} and Ibrahim, {Noor Baa'yah} and Sidek, {Hasidah Mohd.} and Noorani, {Mohd Salmi Md} and Norbert Simon",
booktitle = "2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium",

}

TY - GEN

T1 - Studies on the molar conductivity behavior of PMMA-co- MA electrolyte solution at different polymer concentrations

AU - Hanibah, Hussein

AU - Ahmad, Azizan

AU - Hassan, Nur Hasyareeda

PY - 2014/1/1

Y1 - 2014/1/1

N2 - Polymer is an important constituent of liquid polymer electrolyte along with salt and solvent. The limiting molar conductivity (A 0 ) and equilibrium constant (K eq ) for LiC10 4 in PMMA-co-MA solution was studied at 25.0 °C. Both A 0 and K eq were determined after Oswald's dilution law for a range of PMMA-co-MA concentrations (0.0010 - 0.0030 g cm -3 ). It was noticed that, as PMMA-co-MA concentration increased the A0 value showed a decreasing trend. However, this decreasing trend did not cause any significant improvement in total LiC10 4 dissociation for the electrolyte. This is supported by almost constant K eq values for the range of PMMA-co-MA concentration was at the same order of magnitude. The constant K eq with a decreasing A 0 might due to the formation of ions aggregation in the electrolyte.

AB - Polymer is an important constituent of liquid polymer electrolyte along with salt and solvent. The limiting molar conductivity (A 0 ) and equilibrium constant (K eq ) for LiC10 4 in PMMA-co-MA solution was studied at 25.0 °C. Both A 0 and K eq were determined after Oswald's dilution law for a range of PMMA-co-MA concentrations (0.0010 - 0.0030 g cm -3 ). It was noticed that, as PMMA-co-MA concentration increased the A0 value showed a decreasing trend. However, this decreasing trend did not cause any significant improvement in total LiC10 4 dissociation for the electrolyte. This is supported by almost constant K eq values for the range of PMMA-co-MA concentration was at the same order of magnitude. The constant K eq with a decreasing A 0 might due to the formation of ions aggregation in the electrolyte.

KW - Liquid polymer electrolyte

KW - PPMA-co-MA

UR - http://www.scopus.com/inward/record.url?scp=85063834808&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85063834808&partnerID=8YFLogxK

U2 - 10.1063/1.4895211

DO - 10.1063/1.4895211

M3 - Conference contribution

T3 - AIP Conference Proceedings

SP - 295

EP - 301

BT - 2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium

A2 - Ibrahim, Zahari

A2 - Maideen, Haja Maideen Kader

A2 - Ibrahim, Nazlina

A2 - Karim, Nurul Huda Abd

A2 - Yusof, Taufik

A2 - Razak, Fatimah Abdul

A2 - Maseran, Nurulkamal

A2 - Khalid, Rozida Mohd

A2 - Ibrahim, Noor Baa'yah

A2 - Sidek, Hasidah Mohd.

A2 - Noorani, Mohd Salmi Md

A2 - Simon, Norbert

PB - American Institute of Physics Inc.

ER -