Studies on electrochemical behaviour of PVdF-HFP based ionic liquid gel polymer electrolyte

M. Z. Dzulkipli, Azizan Ahmad, Mohd Sukor Su'ait, S. A.M. Noor, N. A. Dzulkurnain, J. Karim, Nur Hasyareeda Hassan

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Ionic liquid gel polymer electrolyte (ILGPE) film consisting of poly(vinylidene fluoride-hexafluoropropylene) (PVdF-HFP) and 1-butyl-3-methylimidazolium tetrafluoroborate [Bmim][BF4] with different composition ratio were prepared through solution casting technique. The prepared films were subjected to impedance, temperature dependence, and total ionic transference number analysis. Ionic conductivity for each ILGPEs were measured at room temperature and with increasing temperature ranging from 303 to 373K. The maximum room temperature ionic conductivity is found to be 2.84 × 10-3 S cm-1 for film containing 60% composition ratio of [Bmim][BF4]. Temperature dependence analysis showed that the ionic conductivity of the ILGPEs increased with increasing temperature and seem to obey Arrhenius behaviour. Total ionic transference number showed that ions are the major charge carriers in this system.

Original languageEnglish
Title of host publication2018 UKM FST Postgraduate Colloquium
Subtitle of host publicationProceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2018 Postgraduate Colloquium
EditorsNoor Hayati Ahmad Rasol, Kamarulzaman Ibrahim, Siti Aishah Hasbullah, Mohammad Hafizuddin Hj. Jumali, Nazlina Ibrahim, Marlia Mohd Hanafiah, Mohd Talib Latif
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735418431
DOIs
Publication statusPublished - 27 Jun 2019
Event2018 UKM FST Postgraduate Colloquium - Selangor, Malaysia
Duration: 4 Apr 20186 Apr 2018

Publication series

NameAIP Conference Proceedings
Volume2111
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference2018 UKM FST Postgraduate Colloquium
CountryMalaysia
CitySelangor
Period4/4/186/4/18

Fingerprint

vinylidene
fluorides
films (materials)
fluoride
electrolyte
ion currents
electrolytes
polymers
gel
polymer
gels
liquids
ambient temperature
temperature dependence
temperature
conductivity
room temperature
charge carriers
impedance
ions

ASJC Scopus subject areas

  • Ecology, Evolution, Behavior and Systematics
  • Ecology
  • Plant Science
  • Physics and Astronomy(all)
  • Nature and Landscape Conservation

Cite this

Dzulkipli, M. Z., Ahmad, A., Su'ait, M. S., Noor, S. A. M., Dzulkurnain, N. A., Karim, J., & Hassan, N. H. (2019). Studies on electrochemical behaviour of PVdF-HFP based ionic liquid gel polymer electrolyte. In N. H. A. Rasol, K. Ibrahim, S. A. Hasbullah, M. H. H. Jumali, N. Ibrahim, M. M. Hanafiah, & M. T. Latif (Eds.), 2018 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2018 Postgraduate Colloquium [050006] (AIP Conference Proceedings; Vol. 2111). American Institute of Physics Inc.. https://doi.org/10.1063/1.5111254

Studies on electrochemical behaviour of PVdF-HFP based ionic liquid gel polymer electrolyte. / Dzulkipli, M. Z.; Ahmad, Azizan; Su'ait, Mohd Sukor; Noor, S. A.M.; Dzulkurnain, N. A.; Karim, J.; Hassan, Nur Hasyareeda.

2018 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2018 Postgraduate Colloquium. ed. / Noor Hayati Ahmad Rasol; Kamarulzaman Ibrahim; Siti Aishah Hasbullah; Mohammad Hafizuddin Hj. Jumali; Nazlina Ibrahim; Marlia Mohd Hanafiah; Mohd Talib Latif. American Institute of Physics Inc., 2019. 050006 (AIP Conference Proceedings; Vol. 2111).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Dzulkipli, MZ, Ahmad, A, Su'ait, MS, Noor, SAM, Dzulkurnain, NA, Karim, J & Hassan, NH 2019, Studies on electrochemical behaviour of PVdF-HFP based ionic liquid gel polymer electrolyte. in NHA Rasol, K Ibrahim, SA Hasbullah, MHH Jumali, N Ibrahim, MM Hanafiah & MT Latif (eds), 2018 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2018 Postgraduate Colloquium., 050006, AIP Conference Proceedings, vol. 2111, American Institute of Physics Inc., 2018 UKM FST Postgraduate Colloquium, Selangor, Malaysia, 4/4/18. https://doi.org/10.1063/1.5111254
Dzulkipli MZ, Ahmad A, Su'ait MS, Noor SAM, Dzulkurnain NA, Karim J et al. Studies on electrochemical behaviour of PVdF-HFP based ionic liquid gel polymer electrolyte. In Rasol NHA, Ibrahim K, Hasbullah SA, Jumali MHH, Ibrahim N, Hanafiah MM, Latif MT, editors, 2018 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2018 Postgraduate Colloquium. American Institute of Physics Inc. 2019. 050006. (AIP Conference Proceedings). https://doi.org/10.1063/1.5111254
Dzulkipli, M. Z. ; Ahmad, Azizan ; Su'ait, Mohd Sukor ; Noor, S. A.M. ; Dzulkurnain, N. A. ; Karim, J. ; Hassan, Nur Hasyareeda. / Studies on electrochemical behaviour of PVdF-HFP based ionic liquid gel polymer electrolyte. 2018 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2018 Postgraduate Colloquium. editor / Noor Hayati Ahmad Rasol ; Kamarulzaman Ibrahim ; Siti Aishah Hasbullah ; Mohammad Hafizuddin Hj. Jumali ; Nazlina Ibrahim ; Marlia Mohd Hanafiah ; Mohd Talib Latif. American Institute of Physics Inc., 2019. (AIP Conference Proceedings).
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N2 - Ionic liquid gel polymer electrolyte (ILGPE) film consisting of poly(vinylidene fluoride-hexafluoropropylene) (PVdF-HFP) and 1-butyl-3-methylimidazolium tetrafluoroborate [Bmim][BF4] with different composition ratio were prepared through solution casting technique. The prepared films were subjected to impedance, temperature dependence, and total ionic transference number analysis. Ionic conductivity for each ILGPEs were measured at room temperature and with increasing temperature ranging from 303 to 373K. The maximum room temperature ionic conductivity is found to be 2.84 × 10-3 S cm-1 for film containing 60% composition ratio of [Bmim][BF4]. Temperature dependence analysis showed that the ionic conductivity of the ILGPEs increased with increasing temperature and seem to obey Arrhenius behaviour. Total ionic transference number showed that ions are the major charge carriers in this system.

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