Studies of Fe metal carburization by carbon monoxide using XRD and TPR techniques

Norliza Dzakaria, Fairous Salleh, Tengku Shafazila Tengku Saharuddin, Alinda Samsuri, Azizul Hakim, Wan Isahak Wan Nor Roslam, Mohamed Wahab Mohamed Hisham, Mohd. Ambar Yarmo

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

This study was undertaken to investigate the effect of carburization of metallic Fe by (20%,v/v) carbon monoxide (CO). Carburization of Fe by carbon monoxide was examined by using temperature-programmed reduction (TPR), X-ray powder diffractometry (XRD) and Carbon Hydrogen Nitrogen Sulfur (CHNS) technique. Based on a thermodynamic calculation, the free energy Gibb’s value to produce carbon is-8.08 kcal/mol which are favorable. However, production of iron carbide from the same reaction, the free energy Gibb’s value is +9.24 kcal/mol which is not feasible. From the XRD results, shows that after carburization of Fe, the peak appears only for Fe but there is a broad peak between 20-30°. The peak might be indicated as carbon in amorphous form. This finding is supported by the percent of carbon content in CHNS analysis which are increasing when the temperature is increased. This shows that after carburization the carbon content is increasing with increasing in temperature due to carbon deposited on metallic iron. In this research, three different temperatures were used which are 300 °C, 500 °C and 700 °C.

Original languageEnglish
Title of host publicationCurrent Material Research Using X-Rays and Related Techniques II
PublisherTrans Tech Publications Ltd
Pages524-528
Number of pages5
Volume888 MSF
ISBN (Print)9783035710298
DOIs
Publication statusPublished - 2017
EventInternational Conference on X-Rays and Related Techniques in Research and Industry, ICXRI 2016 - Putrajaya, Malaysia
Duration: 17 Aug 201618 Aug 2016

Publication series

NameMaterials Science Forum
Volume888 MSF
ISSN (Print)02555476

Other

OtherInternational Conference on X-Rays and Related Techniques in Research and Industry, ICXRI 2016
CountryMalaysia
CityPutrajaya
Period17/8/1618/8/16

Fingerprint

Carbon Monoxide
Carbon monoxide
Powders
carbon monoxide
Carbon
Metals
X rays
carbon
metals
x rays
Temperature
Gibbs free energy
temperature
Sulfur
Hydrogen
Nitrogen
sulfur
Iron
iron
nitrogen

Keywords

  • Carbon monoxide
  • Carburization
  • Fe
  • TPR
  • XRD

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Dzakaria, N., Salleh, F., Tengku Saharuddin, T. S., Samsuri, A., Hakim, A., Wan Nor Roslam, W. I., ... Yarmo, M. A. (2017). Studies of Fe metal carburization by carbon monoxide using XRD and TPR techniques. In Current Material Research Using X-Rays and Related Techniques II (Vol. 888 MSF, pp. 524-528). (Materials Science Forum; Vol. 888 MSF). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/MSF.888.524

Studies of Fe metal carburization by carbon monoxide using XRD and TPR techniques. / Dzakaria, Norliza; Salleh, Fairous; Tengku Saharuddin, Tengku Shafazila; Samsuri, Alinda; Hakim, Azizul; Wan Nor Roslam, Wan Isahak; Mohamed Hisham, Mohamed Wahab; Yarmo, Mohd. Ambar.

Current Material Research Using X-Rays and Related Techniques II. Vol. 888 MSF Trans Tech Publications Ltd, 2017. p. 524-528 (Materials Science Forum; Vol. 888 MSF).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Dzakaria, N, Salleh, F, Tengku Saharuddin, TS, Samsuri, A, Hakim, A, Wan Nor Roslam, WI, Mohamed Hisham, MW & Yarmo, MA 2017, Studies of Fe metal carburization by carbon monoxide using XRD and TPR techniques. in Current Material Research Using X-Rays and Related Techniques II. vol. 888 MSF, Materials Science Forum, vol. 888 MSF, Trans Tech Publications Ltd, pp. 524-528, International Conference on X-Rays and Related Techniques in Research and Industry, ICXRI 2016, Putrajaya, Malaysia, 17/8/16. https://doi.org/10.4028/www.scientific.net/MSF.888.524
Dzakaria N, Salleh F, Tengku Saharuddin TS, Samsuri A, Hakim A, Wan Nor Roslam WI et al. Studies of Fe metal carburization by carbon monoxide using XRD and TPR techniques. In Current Material Research Using X-Rays and Related Techniques II. Vol. 888 MSF. Trans Tech Publications Ltd. 2017. p. 524-528. (Materials Science Forum). https://doi.org/10.4028/www.scientific.net/MSF.888.524
Dzakaria, Norliza ; Salleh, Fairous ; Tengku Saharuddin, Tengku Shafazila ; Samsuri, Alinda ; Hakim, Azizul ; Wan Nor Roslam, Wan Isahak ; Mohamed Hisham, Mohamed Wahab ; Yarmo, Mohd. Ambar. / Studies of Fe metal carburization by carbon monoxide using XRD and TPR techniques. Current Material Research Using X-Rays and Related Techniques II. Vol. 888 MSF Trans Tech Publications Ltd, 2017. pp. 524-528 (Materials Science Forum).
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