Structure and fungicidal activity of some Diorganotin(IV) with 2-thioacetic-5-phenyl-1,3,4-oxadiazole and benzamidophenylalanine

Emad Yousif, Yang Farina Abdul Aziz, Abdulbasit Graisa, Nadia Salih, Jumat Salimon

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

New diorganotin(IV) complexes of the type Ph2SnL2, Bu2SnL2 and Me2SnL2 of the ligands 2-thioacetic-5-phenyl-1,3,4-oxadiazole (HL1) and benzamidophenylalanine (HL2). Have been synthesized and characterized by physico-chemical techniques such as (elemental analysis, and electrolytic conductance) and spectral UV-Visible, IR and 1H, 13C and 119Sn NMR). Monomer structures for the complexes, bidentate and octahedral geometry was proposed for the prepared complexes. Preliminary in vitro tests for fungicidal activity show that all prepared compounds display good fungicidal activity to Gibberela, Cercospora arachidicola, Physolospora piricola and Fusarium oxysporum. Moreover, the Ph2Sn(L2)2 shows a higher fungicide activity than diorganotin carboxylate.

Original languageEnglish
Pages (from-to)67-72
Number of pages6
JournalIranian Journal of Chemistry and Chemical Engineering
Volume30
Issue number2
Publication statusPublished - 2011

Fingerprint

Fungicides
Monomers
Ligands
Nuclear magnetic resonance
Geometry
Chemical analysis
1,3,4-oxadiazole

Keywords

  • Carboxylate
  • Diorganotin(IV)
  • Fungicidal activity
  • Spectral studies

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Structure and fungicidal activity of some Diorganotin(IV) with 2-thioacetic-5-phenyl-1,3,4-oxadiazole and benzamidophenylalanine. / Yousif, Emad; Abdul Aziz, Yang Farina; Graisa, Abdulbasit; Salih, Nadia; Salimon, Jumat.

In: Iranian Journal of Chemistry and Chemical Engineering, Vol. 30, No. 2, 2011, p. 67-72.

Research output: Contribution to journalArticle

@article{769d97a36a5444ba97e5c2ea37b013cc,
title = "Structure and fungicidal activity of some Diorganotin(IV) with 2-thioacetic-5-phenyl-1,3,4-oxadiazole and benzamidophenylalanine",
abstract = "New diorganotin(IV) complexes of the type Ph2SnL2, Bu2SnL2 and Me2SnL2 of the ligands 2-thioacetic-5-phenyl-1,3,4-oxadiazole (HL1) and benzamidophenylalanine (HL2). Have been synthesized and characterized by physico-chemical techniques such as (elemental analysis, and electrolytic conductance) and spectral UV-Visible, IR and 1H, 13C and 119Sn NMR). Monomer structures for the complexes, bidentate and octahedral geometry was proposed for the prepared complexes. Preliminary in vitro tests for fungicidal activity show that all prepared compounds display good fungicidal activity to Gibberela, Cercospora arachidicola, Physolospora piricola and Fusarium oxysporum. Moreover, the Ph2Sn(L2)2 shows a higher fungicide activity than diorganotin carboxylate.",
keywords = "Carboxylate, Diorganotin(IV), Fungicidal activity, Spectral studies",
author = "Emad Yousif and {Abdul Aziz}, {Yang Farina} and Abdulbasit Graisa and Nadia Salih and Jumat Salimon",
year = "2011",
language = "English",
volume = "30",
pages = "67--72",
journal = "Iranian Journal of Chemistry and Chemical Engineering",
issn = "1021-9986",
publisher = "Iranian Journal of Chemistry and Chemical Engineering",
number = "2",

}

TY - JOUR

T1 - Structure and fungicidal activity of some Diorganotin(IV) with 2-thioacetic-5-phenyl-1,3,4-oxadiazole and benzamidophenylalanine

AU - Yousif, Emad

AU - Abdul Aziz, Yang Farina

AU - Graisa, Abdulbasit

AU - Salih, Nadia

AU - Salimon, Jumat

PY - 2011

Y1 - 2011

N2 - New diorganotin(IV) complexes of the type Ph2SnL2, Bu2SnL2 and Me2SnL2 of the ligands 2-thioacetic-5-phenyl-1,3,4-oxadiazole (HL1) and benzamidophenylalanine (HL2). Have been synthesized and characterized by physico-chemical techniques such as (elemental analysis, and electrolytic conductance) and spectral UV-Visible, IR and 1H, 13C and 119Sn NMR). Monomer structures for the complexes, bidentate and octahedral geometry was proposed for the prepared complexes. Preliminary in vitro tests for fungicidal activity show that all prepared compounds display good fungicidal activity to Gibberela, Cercospora arachidicola, Physolospora piricola and Fusarium oxysporum. Moreover, the Ph2Sn(L2)2 shows a higher fungicide activity than diorganotin carboxylate.

AB - New diorganotin(IV) complexes of the type Ph2SnL2, Bu2SnL2 and Me2SnL2 of the ligands 2-thioacetic-5-phenyl-1,3,4-oxadiazole (HL1) and benzamidophenylalanine (HL2). Have been synthesized and characterized by physico-chemical techniques such as (elemental analysis, and electrolytic conductance) and spectral UV-Visible, IR and 1H, 13C and 119Sn NMR). Monomer structures for the complexes, bidentate and octahedral geometry was proposed for the prepared complexes. Preliminary in vitro tests for fungicidal activity show that all prepared compounds display good fungicidal activity to Gibberela, Cercospora arachidicola, Physolospora piricola and Fusarium oxysporum. Moreover, the Ph2Sn(L2)2 shows a higher fungicide activity than diorganotin carboxylate.

KW - Carboxylate

KW - Diorganotin(IV)

KW - Fungicidal activity

KW - Spectral studies

UR - http://www.scopus.com/inward/record.url?scp=81855226455&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=81855226455&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:81855226455

VL - 30

SP - 67

EP - 72

JO - Iranian Journal of Chemistry and Chemical Engineering

JF - Iranian Journal of Chemistry and Chemical Engineering

SN - 1021-9986

IS - 2

ER -