Selective ozonolysis of cis-crotamiton

Free catalyzed oxidative synthesis of n-ethyl-n-(o-tolyl)formamide as a new compound

Ahmed A. Al-Amiery, Bilal Wasmi, Abdul Amir H. Kadhum, Abu Bakar Mohamad

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

A novel method for the synthesis of a N-ethyl-N-(o-tolyl)formamide was described which involves ozonolysis of a cis-crotamiton. The reaction proceeds via ozone attack on the enolic double bond, cleavage, and aldehyde formation through the free hydroxyl group. The present study establishes the conditions for selective ozonolysis of cis-crotamiton, leading to N-ethyl-N-(o-tolyl)formamide 2 (55.7%). The N-ethyl-N-(o-tolyl)formamide was characterized by spectroscopical techniques

Original languageEnglish
Pages (from-to)385-390
Number of pages6
JournalOzone: Science and Engineering
Volume37
Issue number4
DOIs
Publication statusPublished - 1 Jan 2015

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aldehyde
Aldehydes
Ozone
cleavage
ozone
Hydroxyl Radical
method
crotamiton
formamide

Keywords

  • Crotamiton
  • N-Ethyl-N-(o-tolyl)formamide
  • Ozone
  • Ozonolysis

ASJC Scopus subject areas

  • Environmental Chemistry
  • Environmental Engineering

Cite this

Selective ozonolysis of cis-crotamiton : Free catalyzed oxidative synthesis of n-ethyl-n-(o-tolyl)formamide as a new compound. / Al-Amiery, Ahmed A.; Wasmi, Bilal; Kadhum, Abdul Amir H.; Mohamad, Abu Bakar.

In: Ozone: Science and Engineering, Vol. 37, No. 4, 01.01.2015, p. 385-390.

Research output: Contribution to journalArticle

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