[Ru(bpy)3]Cl2-catalyzed aerobic oxidative cleavage β-diketones to carboxylic acids under visible light irradiation

Xiao Yan Wang, Zhen Peng Shang, Gao Feng Zha, Xiao Qing Chen, Bukhari Syed Nasir Abbas, Hua Li Qin

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

A mild and highly efficient method for the preparation of carboxylic acids is developed through a visible-light-mediated aerobic oxidative cleavage of β-diketones. This process provides a potential general, practical and scalable protocol for both laboratory synthesis and industrial production of carboxylic acids in a green manner.

Original languageEnglish
Pages (from-to)5628-5631
Number of pages4
JournalTetrahedron Letters
Volume57
Issue number50
DOIs
Publication statusPublished - 14 Dec 2016
Externally publishedYes

Fingerprint

Carboxylic Acids
Irradiation
Light
tris(2,2'-bipyridyl)ruthenium(II)

Keywords

  • Carboxylic acids
  • Oxidative cleavage
  • Photoredox
  • β-Diketones

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

[Ru(bpy)3]Cl2-catalyzed aerobic oxidative cleavage β-diketones to carboxylic acids under visible light irradiation. / Wang, Xiao Yan; Shang, Zhen Peng; Zha, Gao Feng; Chen, Xiao Qing; Syed Nasir Abbas, Bukhari; Qin, Hua Li.

In: Tetrahedron Letters, Vol. 57, No. 50, 14.12.2016, p. 5628-5631.

Research output: Contribution to journalArticle

Wang, Xiao Yan ; Shang, Zhen Peng ; Zha, Gao Feng ; Chen, Xiao Qing ; Syed Nasir Abbas, Bukhari ; Qin, Hua Li. / [Ru(bpy)3]Cl2-catalyzed aerobic oxidative cleavage β-diketones to carboxylic acids under visible light irradiation. In: Tetrahedron Letters. 2016 ; Vol. 57, No. 50. pp. 5628-5631.
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