Role of salt concentration lithium perchlorate on ionic conductivity and structural of (glycidyl methacrylate -co-ethyl methacrylate) (70/30) based on a solid polymer electrolyte

Research output: Chapter in Book/Report/Conference proceedingConference contribution

4 Citations (Scopus)

Abstract

A new solid polymer electrolytes (SPE) comprising copolymer of poly(glycidyl methacrylate, GMA) and (ethyl methacrylate, EMA) as polymer host and LiClO4 as dopant was prepared by solution-casting technique. The copolymer was prepared by photopolymerization method and was characterized using NMR. The SPEs were characterized using electrochemical impedance spectroscopy (EIS), fourier transforms infrared (FTIR) and X-ray diffraction (XRD). The highest conductivity achieved was 4.0x10-4 at 373K with highest conductivity at room temperature (2.7x10-5 S cm-1 at 30 wt. % of LiClO4). The active coordination site for the cation (Li+), three electrons donating functional carbonyl, ether and epoxy group of the GMA-co-EMA host have been evaluated base on their properties that were recorded in (FTIR). The structural analysis showed reduction in copolymer crystallinity phases at its highest conductivity.

Original languageEnglish
Title of host publicationAdvanced Materials Research
Pages454-458
Number of pages5
Volume626
DOIs
Publication statusPublished - 2013
Event2012 International Conference on Advanced Materials Engineering and Technology, ICAMET 2012 - Penang
Duration: 28 Nov 201230 Nov 2012

Publication series

NameAdvanced Materials Research
Volume626
ISSN (Print)10226680

Other

Other2012 International Conference on Advanced Materials Engineering and Technology, ICAMET 2012
CityPenang
Period28/11/1230/11/12

Fingerprint

Ionic conductivity
Lithium
Copolymers
Electrolytes
Salts
Fourier transforms
Polymers
Infrared radiation
Photopolymerization
Electrochemical impedance spectroscopy
Structural analysis
Ethers
Casting
Positive ions
Doping (additives)
Nuclear magnetic resonance
X ray diffraction
Electrons
Temperature

Keywords

  • Ethyl methacylate
  • Glycidyl methacrylate
  • Ionic conductivity
  • Lithium ion battery

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Role of salt concentration lithium perchlorate on ionic conductivity and structural of (glycidyl methacrylate -co-ethyl methacrylate) (70/30) based on a solid polymer electrolyte. / Imperiyka, M.; Ahmad, Azizan; Abu Hanifah, Sharina; Abd Rahman, Mohd Yusri.

Advanced Materials Research. Vol. 626 2013. p. 454-458 (Advanced Materials Research; Vol. 626).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Imperiyka, M, Ahmad, A, Abu Hanifah, S & Abd Rahman, MY 2013, Role of salt concentration lithium perchlorate on ionic conductivity and structural of (glycidyl methacrylate -co-ethyl methacrylate) (70/30) based on a solid polymer electrolyte. in Advanced Materials Research. vol. 626, Advanced Materials Research, vol. 626, pp. 454-458, 2012 International Conference on Advanced Materials Engineering and Technology, ICAMET 2012, Penang, 28/11/12. https://doi.org/10.4028/www.scientific.net/AMR.626.454
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abstract = "A new solid polymer electrolytes (SPE) comprising copolymer of poly(glycidyl methacrylate, GMA) and (ethyl methacrylate, EMA) as polymer host and LiClO4 as dopant was prepared by solution-casting technique. The copolymer was prepared by photopolymerization method and was characterized using NMR. The SPEs were characterized using electrochemical impedance spectroscopy (EIS), fourier transforms infrared (FTIR) and X-ray diffraction (XRD). The highest conductivity achieved was 4.0x10-4 at 373K with highest conductivity at room temperature (2.7x10-5 S cm-1 at 30 wt. {\%} of LiClO4). The active coordination site for the cation (Li+), three electrons donating functional carbonyl, ether and epoxy group of the GMA-co-EMA host have been evaluated base on their properties that were recorded in (FTIR). The structural analysis showed reduction in copolymer crystallinity phases at its highest conductivity.",
keywords = "Ethyl methacylate, Glycidyl methacrylate, Ionic conductivity, Lithium ion battery",
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AU - Ahmad, Azizan

AU - Abu Hanifah, Sharina

AU - Abd Rahman, Mohd Yusri

PY - 2013

Y1 - 2013

N2 - A new solid polymer electrolytes (SPE) comprising copolymer of poly(glycidyl methacrylate, GMA) and (ethyl methacrylate, EMA) as polymer host and LiClO4 as dopant was prepared by solution-casting technique. The copolymer was prepared by photopolymerization method and was characterized using NMR. The SPEs were characterized using electrochemical impedance spectroscopy (EIS), fourier transforms infrared (FTIR) and X-ray diffraction (XRD). The highest conductivity achieved was 4.0x10-4 at 373K with highest conductivity at room temperature (2.7x10-5 S cm-1 at 30 wt. % of LiClO4). The active coordination site for the cation (Li+), three electrons donating functional carbonyl, ether and epoxy group of the GMA-co-EMA host have been evaluated base on their properties that were recorded in (FTIR). The structural analysis showed reduction in copolymer crystallinity phases at its highest conductivity.

AB - A new solid polymer electrolytes (SPE) comprising copolymer of poly(glycidyl methacrylate, GMA) and (ethyl methacrylate, EMA) as polymer host and LiClO4 as dopant was prepared by solution-casting technique. The copolymer was prepared by photopolymerization method and was characterized using NMR. The SPEs were characterized using electrochemical impedance spectroscopy (EIS), fourier transforms infrared (FTIR) and X-ray diffraction (XRD). The highest conductivity achieved was 4.0x10-4 at 373K with highest conductivity at room temperature (2.7x10-5 S cm-1 at 30 wt. % of LiClO4). The active coordination site for the cation (Li+), three electrons donating functional carbonyl, ether and epoxy group of the GMA-co-EMA host have been evaluated base on their properties that were recorded in (FTIR). The structural analysis showed reduction in copolymer crystallinity phases at its highest conductivity.

KW - Ethyl methacylate

KW - Glycidyl methacrylate

KW - Ionic conductivity

KW - Lithium ion battery

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