Preparation and characterization of polymer electrolyte of glycidyl methacrylate-methyl methacrylate-LiClO4 plasticized with ethylene carbonate

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Abstract

In the present investigation, we study the properties of the plasticized polyglycidyl methacrylate P(GMA) copolymerized with polymethyl methacrylate P(MMA)-LiClO4 polymer electrolyte prepared by solution casting technique. The electrolyte was characterized using impedance spectroscopy (EIS), Fourier transforms infrared (FTIR), cyclic voltammetry (CV), and X-ray diffraction (XRD). The conductivity was improved from 1.3 × 10 -12 S cm-1 to 8.7 × 10-6 S cm -1 upon the addition of 25 wt.% LiClO4 salt into P(GMA-MMA). The conductivity was improved from 1.4 × 10-6 S cm-1 to 3.0 × 10-4 S cm-1 upon the addition of 80 wt.% EC into P(GMA-MMA)-LiClO4 The band that belongs to C-O-C is shifted farther than the band of C=O upon the addition of LiClO 4 into P(GMA-MMA). The band of C-O-C stretching is shifted to lower wavenumber upon the addition of EC into P(GMA-MMA)-LiClO4. Upon the addition of EC into P(GMA-co-MMA), the intensity of the peaks decreases, implying the amorphous nature of the electrolyte increases with the concentration of the plasticizer. The electrolyte is electrochemically stable at 3.8 V, making it suitable for dye-sensitized solar cell application.

Original languageEnglish
Article number638279
JournalInternational Journal of Polymer Science
Volume2014
DOIs
Publication statusPublished - 2014

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Methacrylates
Electrolytes
Carbonates
Polymers
Ethylene
Plasticizers
Polymethyl Methacrylate
Polymethyl methacrylates
Cyclic voltammetry
Stretching
Fourier transform infrared spectroscopy
Casting
Salts
X ray diffraction
ethylene carbonate
glycidyl methacrylate
lithium perchlorate

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

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title = "Preparation and characterization of polymer electrolyte of glycidyl methacrylate-methyl methacrylate-LiClO4 plasticized with ethylene carbonate",
abstract = "In the present investigation, we study the properties of the plasticized polyglycidyl methacrylate P(GMA) copolymerized with polymethyl methacrylate P(MMA)-LiClO4 polymer electrolyte prepared by solution casting technique. The electrolyte was characterized using impedance spectroscopy (EIS), Fourier transforms infrared (FTIR), cyclic voltammetry (CV), and X-ray diffraction (XRD). The conductivity was improved from 1.3 × 10 -12 S cm-1 to 8.7 × 10-6 S cm -1 upon the addition of 25 wt.{\%} LiClO4 salt into P(GMA-MMA). The conductivity was improved from 1.4 × 10-6 S cm-1 to 3.0 × 10-4 S cm-1 upon the addition of 80 wt.{\%} EC into P(GMA-MMA)-LiClO4 The band that belongs to C-O-C is shifted farther than the band of C=O upon the addition of LiClO 4 into P(GMA-MMA). The band of C-O-C stretching is shifted to lower wavenumber upon the addition of EC into P(GMA-MMA)-LiClO4. Upon the addition of EC into P(GMA-co-MMA), the intensity of the peaks decreases, implying the amorphous nature of the electrolyte increases with the concentration of the plasticizer. The electrolyte is electrochemically stable at 3.8 V, making it suitable for dye-sensitized solar cell application.",
author = "M. Imperiyka and Azizan Ahmad and {Abu Hanifah}, Sharina and {Abd Rahman}, {Mohd Yusri}",
year = "2014",
doi = "10.1155/2014/638279",
language = "English",
volume = "2014",
journal = "International Journal of Polymer Science",
issn = "1687-9422",
publisher = "Hindawi Publishing Corporation",

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T1 - Preparation and characterization of polymer electrolyte of glycidyl methacrylate-methyl methacrylate-LiClO4 plasticized with ethylene carbonate

AU - Imperiyka, M.

AU - Ahmad, Azizan

AU - Abu Hanifah, Sharina

AU - Abd Rahman, Mohd Yusri

PY - 2014

Y1 - 2014

N2 - In the present investigation, we study the properties of the plasticized polyglycidyl methacrylate P(GMA) copolymerized with polymethyl methacrylate P(MMA)-LiClO4 polymer electrolyte prepared by solution casting technique. The electrolyte was characterized using impedance spectroscopy (EIS), Fourier transforms infrared (FTIR), cyclic voltammetry (CV), and X-ray diffraction (XRD). The conductivity was improved from 1.3 × 10 -12 S cm-1 to 8.7 × 10-6 S cm -1 upon the addition of 25 wt.% LiClO4 salt into P(GMA-MMA). The conductivity was improved from 1.4 × 10-6 S cm-1 to 3.0 × 10-4 S cm-1 upon the addition of 80 wt.% EC into P(GMA-MMA)-LiClO4 The band that belongs to C-O-C is shifted farther than the band of C=O upon the addition of LiClO 4 into P(GMA-MMA). The band of C-O-C stretching is shifted to lower wavenumber upon the addition of EC into P(GMA-MMA)-LiClO4. Upon the addition of EC into P(GMA-co-MMA), the intensity of the peaks decreases, implying the amorphous nature of the electrolyte increases with the concentration of the plasticizer. The electrolyte is electrochemically stable at 3.8 V, making it suitable for dye-sensitized solar cell application.

AB - In the present investigation, we study the properties of the plasticized polyglycidyl methacrylate P(GMA) copolymerized with polymethyl methacrylate P(MMA)-LiClO4 polymer electrolyte prepared by solution casting technique. The electrolyte was characterized using impedance spectroscopy (EIS), Fourier transforms infrared (FTIR), cyclic voltammetry (CV), and X-ray diffraction (XRD). The conductivity was improved from 1.3 × 10 -12 S cm-1 to 8.7 × 10-6 S cm -1 upon the addition of 25 wt.% LiClO4 salt into P(GMA-MMA). The conductivity was improved from 1.4 × 10-6 S cm-1 to 3.0 × 10-4 S cm-1 upon the addition of 80 wt.% EC into P(GMA-MMA)-LiClO4 The band that belongs to C-O-C is shifted farther than the band of C=O upon the addition of LiClO 4 into P(GMA-MMA). The band of C-O-C stretching is shifted to lower wavenumber upon the addition of EC into P(GMA-MMA)-LiClO4. Upon the addition of EC into P(GMA-co-MMA), the intensity of the peaks decreases, implying the amorphous nature of the electrolyte increases with the concentration of the plasticizer. The electrolyte is electrochemically stable at 3.8 V, making it suitable for dye-sensitized solar cell application.

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