Preconcentration of trace manganese from natural waters by complexation with dithiocarbamate and adsorption onto C18-solid phase extraction column for neutron activation analysis

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A method was developed for the preconcentration and separation of trace manganese from natural water samples by complexation with dithiocarbamate followed by adsorption onto C18-solid phase extraction column prior to irradiation. The Mn recovery was better than 99.8% without inteference from iron(III) at 5 mg·1-1, copper(II), zinc(II), aluminum(III) and cobalt(II) at 0.5 mg·1-1 and sodium(I), potassium(I), magnesium(II) and calcium(II) at 1 mg·1-1. The separation factor was 100 and the detection limit was 0.01 μg·1-1 with good precision and accuracy with a relative error lower than 3%. The method was applied to the determination of Mn in tap, well, river and treated water samples.

Original languageEnglish
Pages (from-to)257-260
Number of pages4
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume259
Issue number2
DOIs
Publication statusPublished - Feb 2004

Fingerprint

Neutron Activation Analysis
Neutron activation analysis
Solid Phase Extraction
Manganese
Complexation
Adsorption
Water
Cobalt
Aluminum
Rivers
Magnesium
Potassium
Limit of Detection
Zinc
Copper
Calcium
Iron
Sodium
Irradiation
Recovery

ASJC Scopus subject areas

  • Analytical Chemistry
  • Inorganic Chemistry
  • Nuclear Energy and Engineering

Cite this

@article{4344bff6f0c74b5184d460236979c2de,
title = "Preconcentration of trace manganese from natural waters by complexation with dithiocarbamate and adsorption onto C18-solid phase extraction column for neutron activation analysis",
abstract = "A method was developed for the preconcentration and separation of trace manganese from natural water samples by complexation with dithiocarbamate followed by adsorption onto C18-solid phase extraction column prior to irradiation. The Mn recovery was better than 99.8{\%} without inteference from iron(III) at 5 mg·1-1, copper(II), zinc(II), aluminum(III) and cobalt(II) at 0.5 mg·1-1 and sodium(I), potassium(I), magnesium(II) and calcium(II) at 1 mg·1-1. The separation factor was 100 and the detection limit was 0.01 μg·1-1 with good precision and accuracy with a relative error lower than 3{\%}. The method was applied to the determination of Mn in tap, well, river and treated water samples.",
author = "Sukiman Sarmani and Abdullah, {Md. Pauzi} and Bobaker, {A. M.}",
year = "2004",
month = "2",
doi = "10.1023/B:JRNC.0000017298.34598.31",
language = "English",
volume = "259",
pages = "257--260",
journal = "Journal of Radioanalytical Chemistry",
issn = "0022-4081",
publisher = "Elsevier BV",
number = "2",

}

TY - JOUR

T1 - Preconcentration of trace manganese from natural waters by complexation with dithiocarbamate and adsorption onto C18-solid phase extraction column for neutron activation analysis

AU - Sarmani, Sukiman

AU - Abdullah, Md. Pauzi

AU - Bobaker, A. M.

PY - 2004/2

Y1 - 2004/2

N2 - A method was developed for the preconcentration and separation of trace manganese from natural water samples by complexation with dithiocarbamate followed by adsorption onto C18-solid phase extraction column prior to irradiation. The Mn recovery was better than 99.8% without inteference from iron(III) at 5 mg·1-1, copper(II), zinc(II), aluminum(III) and cobalt(II) at 0.5 mg·1-1 and sodium(I), potassium(I), magnesium(II) and calcium(II) at 1 mg·1-1. The separation factor was 100 and the detection limit was 0.01 μg·1-1 with good precision and accuracy with a relative error lower than 3%. The method was applied to the determination of Mn in tap, well, river and treated water samples.

AB - A method was developed for the preconcentration and separation of trace manganese from natural water samples by complexation with dithiocarbamate followed by adsorption onto C18-solid phase extraction column prior to irradiation. The Mn recovery was better than 99.8% without inteference from iron(III) at 5 mg·1-1, copper(II), zinc(II), aluminum(III) and cobalt(II) at 0.5 mg·1-1 and sodium(I), potassium(I), magnesium(II) and calcium(II) at 1 mg·1-1. The separation factor was 100 and the detection limit was 0.01 μg·1-1 with good precision and accuracy with a relative error lower than 3%. The method was applied to the determination of Mn in tap, well, river and treated water samples.

UR - http://www.scopus.com/inward/record.url?scp=1342281516&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=1342281516&partnerID=8YFLogxK

U2 - 10.1023/B:JRNC.0000017298.34598.31

DO - 10.1023/B:JRNC.0000017298.34598.31

M3 - Article

VL - 259

SP - 257

EP - 260

JO - Journal of Radioanalytical Chemistry

JF - Journal of Radioanalytical Chemistry

SN - 0022-4081

IS - 2

ER -