Nucleophilic reactions in strongly acidic media. Highly specific homolytic aromatic alkylation and acylation

Laily Bin Din, Otto Meth-Cohn, Nigel D A Walshe

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Under Minisci reaction conditions, nucleophilic carbon free radicals readily substitute ferrocene (as the ferricinium ion) and protonated acetophenone, the latter reaction being highly positionally specific.

Original languageEnglish
Pages (from-to)4783-4786
Number of pages4
JournalTetrahedron Letters
Volume20
Issue number49
DOIs
Publication statusPublished - 1979
Externally publishedYes

Fingerprint

Acylation
Alkylation
Free Radicals
Carbon
Ions
ferrocene
acetophenone

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Nucleophilic reactions in strongly acidic media. Highly specific homolytic aromatic alkylation and acylation. / Bin Din, Laily; Meth-Cohn, Otto; Walshe, Nigel D A.

In: Tetrahedron Letters, Vol. 20, No. 49, 1979, p. 4783-4786.

Research output: Contribution to journalArticle

Bin Din, Laily ; Meth-Cohn, Otto ; Walshe, Nigel D A. / Nucleophilic reactions in strongly acidic media. Highly specific homolytic aromatic alkylation and acylation. In: Tetrahedron Letters. 1979 ; Vol. 20, No. 49. pp. 4783-4786.
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