Novel approach: Tungsten oxide nanoparticle as a catalyst for malonic acid ester synthesis via ozonolysis

Bilal A. Wasmi, Ahmed A. Al-Amiery, Abdul Amir H. Kadhum, Abu Bakar Mohamad

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Malonic acid ester was synthesized via the one-step ozonolysis of palm olein. Malonic acid ester was spectroscopically characterized using gas chromatography mass spectroscopy (GC-MS). Tungsten oxide nanoparticles were used as the catalyst, which was characterized via X-ray powder diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). Tungsten oxide provided several advantages as a catalyst for the esterification malonic acid such as simple operation for a precise ozonation method, an excellent yield of approximately 10%, short reaction times of 2 h, and reusability due to its recyclability.

Original languageEnglish
Article number715457
JournalJournal of Nanomaterials
Volume2014
DOIs
Publication statusPublished - 2014

Fingerprint

Tungsten
Esters
Nanoparticles
Catalysts
Oxides
Acids
Ozonization
Esterification
Reusability
Gas chromatography
Field emission
X ray powder diffraction
Spectroscopy
Scanning electron microscopy
tungsten oxide
malonic acid

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Novel approach : Tungsten oxide nanoparticle as a catalyst for malonic acid ester synthesis via ozonolysis. / Wasmi, Bilal A.; Al-Amiery, Ahmed A.; Kadhum, Abdul Amir H.; Mohamad, Abu Bakar.

In: Journal of Nanomaterials, Vol. 2014, 715457, 2014.

Research output: Contribution to journalArticle

Wasmi, Bilal A. ; Al-Amiery, Ahmed A. ; Kadhum, Abdul Amir H. ; Mohamad, Abu Bakar. / Novel approach : Tungsten oxide nanoparticle as a catalyst for malonic acid ester synthesis via ozonolysis. In: Journal of Nanomaterials. 2014 ; Vol. 2014.
@article{27dfbd1f2cb84b959602a1987a7a5017,
title = "Novel approach: Tungsten oxide nanoparticle as a catalyst for malonic acid ester synthesis via ozonolysis",
abstract = "Malonic acid ester was synthesized via the one-step ozonolysis of palm olein. Malonic acid ester was spectroscopically characterized using gas chromatography mass spectroscopy (GC-MS). Tungsten oxide nanoparticles were used as the catalyst, which was characterized via X-ray powder diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). Tungsten oxide provided several advantages as a catalyst for the esterification malonic acid such as simple operation for a precise ozonation method, an excellent yield of approximately 10{\%}, short reaction times of 2 h, and reusability due to its recyclability.",
author = "Wasmi, {Bilal A.} and Al-Amiery, {Ahmed A.} and Kadhum, {Abdul Amir H.} and Mohamad, {Abu Bakar}",
year = "2014",
doi = "10.1155/2014/715457",
language = "English",
volume = "2014",
journal = "Journal of Nanomaterials",
issn = "1687-4110",
publisher = "Hindawi Publishing Corporation",

}

TY - JOUR

T1 - Novel approach

T2 - Tungsten oxide nanoparticle as a catalyst for malonic acid ester synthesis via ozonolysis

AU - Wasmi, Bilal A.

AU - Al-Amiery, Ahmed A.

AU - Kadhum, Abdul Amir H.

AU - Mohamad, Abu Bakar

PY - 2014

Y1 - 2014

N2 - Malonic acid ester was synthesized via the one-step ozonolysis of palm olein. Malonic acid ester was spectroscopically characterized using gas chromatography mass spectroscopy (GC-MS). Tungsten oxide nanoparticles were used as the catalyst, which was characterized via X-ray powder diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). Tungsten oxide provided several advantages as a catalyst for the esterification malonic acid such as simple operation for a precise ozonation method, an excellent yield of approximately 10%, short reaction times of 2 h, and reusability due to its recyclability.

AB - Malonic acid ester was synthesized via the one-step ozonolysis of palm olein. Malonic acid ester was spectroscopically characterized using gas chromatography mass spectroscopy (GC-MS). Tungsten oxide nanoparticles were used as the catalyst, which was characterized via X-ray powder diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). Tungsten oxide provided several advantages as a catalyst for the esterification malonic acid such as simple operation for a precise ozonation method, an excellent yield of approximately 10%, short reaction times of 2 h, and reusability due to its recyclability.

UR - http://www.scopus.com/inward/record.url?scp=84934901126&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84934901126&partnerID=8YFLogxK

U2 - 10.1155/2014/715457

DO - 10.1155/2014/715457

M3 - Article

AN - SCOPUS:84934901126

VL - 2014

JO - Journal of Nanomaterials

JF - Journal of Nanomaterials

SN - 1687-4110

M1 - 715457

ER -