Abstract
(Graph Presented) A series of new organotin(IV) dithiocarbamate compounds of type RnSn (S2CNR′R″)4-n (n = 2, 3; R = dimethyl, dibutyl, diphenyl, triphenyl and tert-butyl; R′ = methyl, ethyl, benzyl; R″ = isopropyl, ethyl, ethanol) have been successfully synthesized. Elemental analysis showed that the percentage of the elements conformed to the general formula of these compounds. The important peaks of the infrared spectra for the stretching mode ν(C=N), ν(C=S), and ν(Sn-S) for the compounds were observed in the area of 1440-1480 cm-1, 940-1000 cm-1, and 340-90 cm-1, respectively. The 13C NMR spectra showed the most important peak for N 13CS2 chemical shifts were observed in the range 190-210 ppm. X-ray single crystal studies for several structures of these compounds showed that the chelating mode of the dithiocarbamate groups to the central tin atoms were either bidentate or anisobidentate.
| Original language | English |
|---|---|
| Pages (from-to) | 1326-1329 |
| Number of pages | 4 |
| Journal | Phosphorus, Sulfur and Silicon and the Related Elements |
| Volume | 186 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - Jun 2011 |
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Keywords
- Crystal structure
- dithiocarbamate
- organotin(IV)
ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
- Biochemistry
Cite this
New dithiocarbamate compounds from organotin(IV). / Baba, Ibrahim; Muthalib, Amirah Faizah Abdul; Abdul Aziz, Yang Farina; Weng, Ng Seik.
In: Phosphorus, Sulfur and Silicon and the Related Elements, Vol. 186, No. 6, 06.2011, p. 1326-1329.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - New dithiocarbamate compounds from organotin(IV)
AU - Baba, Ibrahim
AU - Muthalib, Amirah Faizah Abdul
AU - Abdul Aziz, Yang Farina
AU - Weng, Ng Seik
PY - 2011/6
Y1 - 2011/6
N2 - (Graph Presented) A series of new organotin(IV) dithiocarbamate compounds of type RnSn (S2CNR′R″)4-n (n = 2, 3; R = dimethyl, dibutyl, diphenyl, triphenyl and tert-butyl; R′ = methyl, ethyl, benzyl; R″ = isopropyl, ethyl, ethanol) have been successfully synthesized. Elemental analysis showed that the percentage of the elements conformed to the general formula of these compounds. The important peaks of the infrared spectra for the stretching mode ν(C=N), ν(C=S), and ν(Sn-S) for the compounds were observed in the area of 1440-1480 cm-1, 940-1000 cm-1, and 340-90 cm-1, respectively. The 13C NMR spectra showed the most important peak for N 13CS2 chemical shifts were observed in the range 190-210 ppm. X-ray single crystal studies for several structures of these compounds showed that the chelating mode of the dithiocarbamate groups to the central tin atoms were either bidentate or anisobidentate.
AB - (Graph Presented) A series of new organotin(IV) dithiocarbamate compounds of type RnSn (S2CNR′R″)4-n (n = 2, 3; R = dimethyl, dibutyl, diphenyl, triphenyl and tert-butyl; R′ = methyl, ethyl, benzyl; R″ = isopropyl, ethyl, ethanol) have been successfully synthesized. Elemental analysis showed that the percentage of the elements conformed to the general formula of these compounds. The important peaks of the infrared spectra for the stretching mode ν(C=N), ν(C=S), and ν(Sn-S) for the compounds were observed in the area of 1440-1480 cm-1, 940-1000 cm-1, and 340-90 cm-1, respectively. The 13C NMR spectra showed the most important peak for N 13CS2 chemical shifts were observed in the range 190-210 ppm. X-ray single crystal studies for several structures of these compounds showed that the chelating mode of the dithiocarbamate groups to the central tin atoms were either bidentate or anisobidentate.
KW - Crystal structure
KW - dithiocarbamate
KW - organotin(IV)
UR - http://www.scopus.com/inward/record.url?scp=79959381414&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=79959381414&partnerID=8YFLogxK
U2 - 10.1080/10426507.2010.548841
DO - 10.1080/10426507.2010.548841
M3 - Article
AN - SCOPUS:79959381414
VL - 186
SP - 1326
EP - 1329
JO - Phosphorus, Sulfur and Silicon and the Related Elements
JF - Phosphorus, Sulfur and Silicon and the Related Elements
SN - 1042-6507
IS - 6
ER -