New dithiocarbamate compounds from organotin(IV)

Ibrahim Baba, Amirah Faizah Abdul Muthalib, Yang Farina Abdul Aziz, Ng Seik Weng

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

(Graph Presented) A series of new organotin(IV) dithiocarbamate compounds of type RnSn (S2CNR′R″)4-n (n = 2, 3; R = dimethyl, dibutyl, diphenyl, triphenyl and tert-butyl; R′ = methyl, ethyl, benzyl; R″ = isopropyl, ethyl, ethanol) have been successfully synthesized. Elemental analysis showed that the percentage of the elements conformed to the general formula of these compounds. The important peaks of the infrared spectra for the stretching mode ν(C=N), ν(C=S), and ν(Sn-S) for the compounds were observed in the area of 1440-1480 cm-1, 940-1000 cm-1, and 340-90 cm-1, respectively. The 13C NMR spectra showed the most important peak for N 13CS2 chemical shifts were observed in the range 190-210 ppm. X-ray single crystal studies for several structures of these compounds showed that the chelating mode of the dithiocarbamate groups to the central tin atoms were either bidentate or anisobidentate.

Original languageEnglish
Pages (from-to)1326-1329
Number of pages4
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume186
Issue number6
DOIs
Publication statusPublished - Jun 2011

Fingerprint

Organotin Compounds
Tin
Chemical shift
Chelation
Stretching
Ethanol
Nuclear magnetic resonance
X-Rays
Single crystals
Infrared radiation
X rays
Atoms
Chemical analysis
diphenyl
Carbon-13 Magnetic Resonance Spectroscopy

Keywords

  • Crystal structure
  • dithiocarbamate
  • organotin(IV)

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Biochemistry

Cite this

New dithiocarbamate compounds from organotin(IV). / Baba, Ibrahim; Muthalib, Amirah Faizah Abdul; Abdul Aziz, Yang Farina; Weng, Ng Seik.

In: Phosphorus, Sulfur and Silicon and the Related Elements, Vol. 186, No. 6, 06.2011, p. 1326-1329.

Research output: Contribution to journalArticle

Baba, Ibrahim ; Muthalib, Amirah Faizah Abdul ; Abdul Aziz, Yang Farina ; Weng, Ng Seik. / New dithiocarbamate compounds from organotin(IV). In: Phosphorus, Sulfur and Silicon and the Related Elements. 2011 ; Vol. 186, No. 6. pp. 1326-1329.
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