Abstract
A nanocomposite polymer electrolyte consisting of 49% poly(methyl methacrylate)-grafted natural rubber (MG49) as a polymer matrix, lithium tetrafluoroborate (LiBF 4) as a dopant salt, and titanium dioxide (TiO 2) as an inert ceramic filler was prepared by solution casting technique. The ceramic filler, TiO 2, was synthesized in situ by a sol-gel process. The ionic conductivity was investigated by alternating current impedance spectroscopy. X-ray diffraction (XRD) was used to determine the structure of the electrolyte, and its morphology was examined by scanning electron microscopy (SEM). The highest conductivity, 1.4×10 -5 S cm -1 was obtained at 30 wt.% of LiBF4 salt addition with 6 wt.% of TiO 2 filler content. Ionic conductivity was found to increase with the increase of salt concentration. The optimum value of conductivity was found at 6 wt.% of TiO 2. The XRD analysis revealed that the crystalline phase of the polymer host slightly decreased with the addition of salt and filler. The SEM analysis showed that the smoother the surface of the electrolyte, the higher its conductivity.
Original language | English |
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Pages (from-to) | 2611-2618 |
Number of pages | 8 |
Journal | Journal of Solid State Electrochemistry |
Volume | 15 |
Issue number | 11-12 |
DOIs | |
Publication status | Published - Dec 2011 |
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Keywords
- 49% poly(methyl methacrylate)-grafted natural rubber (MG49)
- Ionic conductivity
- Morphology
- Nanocomposite polymer electrolyte (NCPE)
- XRD
ASJC Scopus subject areas
- Electrochemistry
- Electrical and Electronic Engineering
- Condensed Matter Physics
- Materials Science(all)
Cite this
Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4). / Low, S. P.; Ahmad, Azizan; Hamzah, H.; Abd Rahman, Mohd Yusri.
In: Journal of Solid State Electrochemistry, Vol. 15, No. 11-12, 12.2011, p. 2611-2618.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4)
AU - Low, S. P.
AU - Ahmad, Azizan
AU - Hamzah, H.
AU - Abd Rahman, Mohd Yusri
PY - 2011/12
Y1 - 2011/12
N2 - A nanocomposite polymer electrolyte consisting of 49% poly(methyl methacrylate)-grafted natural rubber (MG49) as a polymer matrix, lithium tetrafluoroborate (LiBF 4) as a dopant salt, and titanium dioxide (TiO 2) as an inert ceramic filler was prepared by solution casting technique. The ceramic filler, TiO 2, was synthesized in situ by a sol-gel process. The ionic conductivity was investigated by alternating current impedance spectroscopy. X-ray diffraction (XRD) was used to determine the structure of the electrolyte, and its morphology was examined by scanning electron microscopy (SEM). The highest conductivity, 1.4×10 -5 S cm -1 was obtained at 30 wt.% of LiBF4 salt addition with 6 wt.% of TiO 2 filler content. Ionic conductivity was found to increase with the increase of salt concentration. The optimum value of conductivity was found at 6 wt.% of TiO 2. The XRD analysis revealed that the crystalline phase of the polymer host slightly decreased with the addition of salt and filler. The SEM analysis showed that the smoother the surface of the electrolyte, the higher its conductivity.
AB - A nanocomposite polymer electrolyte consisting of 49% poly(methyl methacrylate)-grafted natural rubber (MG49) as a polymer matrix, lithium tetrafluoroborate (LiBF 4) as a dopant salt, and titanium dioxide (TiO 2) as an inert ceramic filler was prepared by solution casting technique. The ceramic filler, TiO 2, was synthesized in situ by a sol-gel process. The ionic conductivity was investigated by alternating current impedance spectroscopy. X-ray diffraction (XRD) was used to determine the structure of the electrolyte, and its morphology was examined by scanning electron microscopy (SEM). The highest conductivity, 1.4×10 -5 S cm -1 was obtained at 30 wt.% of LiBF4 salt addition with 6 wt.% of TiO 2 filler content. Ionic conductivity was found to increase with the increase of salt concentration. The optimum value of conductivity was found at 6 wt.% of TiO 2. The XRD analysis revealed that the crystalline phase of the polymer host slightly decreased with the addition of salt and filler. The SEM analysis showed that the smoother the surface of the electrolyte, the higher its conductivity.
KW - 49% poly(methyl methacrylate)-grafted natural rubber (MG49)
KW - Ionic conductivity
KW - Morphology
KW - Nanocomposite polymer electrolyte (NCPE)
KW - XRD
UR - http://www.scopus.com/inward/record.url?scp=84855538411&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84855538411&partnerID=8YFLogxK
U2 - 10.1007/s10008-010-1252-0
DO - 10.1007/s10008-010-1252-0
M3 - Article
AN - SCOPUS:84855538411
VL - 15
SP - 2611
EP - 2618
JO - Journal of Solid State Electrochemistry
JF - Journal of Solid State Electrochemistry
SN - 1432-8488
IS - 11-12
ER -