(N-sec-Butyl-N-n-propyldithio-carbamato-κ2S,S′) triphenyltin(IV)

Normah Awang, Ibrahim Baba, Bohari Mohd. Yamin, Seik Weng Ng, Edward R T Tiekink

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The Sn atom in the title compound, [Sn(C6H5) 3(C8H16NS2)], is pentacoordinated by two S atoms, derived from an asymmetrically coordinating dithio-carbamate ligand, and three ipso-C atoms. The coordination geometry is intermediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. The presence of close intramolecular C-H⋯S contacts preclude the S atoms from forming significant intermolecular interactions. Rather, molecules are consolidated in the crystal structure by C-H⋯π inter-actions.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number9
DOIs
Publication statusPublished - Sep 2010

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Atoms
atoms
Carbamates
Crystal structure
Ligands
ligands
crystal structure
Molecules
Geometry
triphenyltin
geometry
molecules
interactions

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

(N-sec-Butyl-N-n-propyldithio-carbamato-κ2S,S′) triphenyltin(IV). / Awang, Normah; Baba, Ibrahim; Mohd. Yamin, Bohari; Ng, Seik Weng; Tiekink, Edward R T.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 66, No. 9, 09.2010.

Research output: Contribution to journalArticle

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