N-[N-(furan-2-carbonyl)hydrazinothio-carbonyl]benzamide

Bohari Mohd. Yamin, M. Sukeri M Yusof

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The title compound, C13H11N3O 3S, adopts a cis-trans conformation, where the furoyl moiety and the benzoyl group lie respectively cis and trans relative to the S atom across the thiourea C - N bonds. Both H atoms belonging to the hydrazine moiety participate in intramolecular hydrogen bonds; one of them forms an N - H⋯O bond and closes the six-membered pseudo-ring, whereas the other one participates in N - H⋯O and N - H⋯S bonds, forming two five-membered pseudo-rings. The molecules in the crystal are linked by N - H⋯O and C - H⋯O intermolecular hydrogen bonds involving the amide and phenyl H atoms and the O atoms of the furoyl and benzoyl groups. The intermolecular hydrogen bonds give rise to infinite chains running along the c axis of the crystal.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number2
DOIs
Publication statusPublished - Feb 2003

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furans
Hydrogen
hydrazine
Atoms
Hydrogen bonds
hydrogen bonds
atoms
Thiourea
Amides
Crystals
Thioureas
rings
Hydrazine
thioureas
hydrazines
amides
crystals
Conformations
Molecules
benzamide

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

N-[N-(furan-2-carbonyl)hydrazinothio-carbonyl]benzamide. / Mohd. Yamin, Bohari; Yusof, M. Sukeri M.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, No. 2, 02.2003.

Research output: Contribution to journalArticle

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AB - The title compound, C13H11N3O 3S, adopts a cis-trans conformation, where the furoyl moiety and the benzoyl group lie respectively cis and trans relative to the S atom across the thiourea C - N bonds. Both H atoms belonging to the hydrazine moiety participate in intramolecular hydrogen bonds; one of them forms an N - H⋯O bond and closes the six-membered pseudo-ring, whereas the other one participates in N - H⋯O and N - H⋯S bonds, forming two five-membered pseudo-rings. The molecules in the crystal are linked by N - H⋯O and C - H⋯O intermolecular hydrogen bonds involving the amide and phenyl H atoms and the O atoms of the furoyl and benzoyl groups. The intermolecular hydrogen bonds give rise to infinite chains running along the c axis of the crystal.

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