N-Butyldichlorido{4-cyclohexyl-1-[phenyl(2-pyridyl-N)methylene] -thiosemicarbazidato-κ2N1,S}tin(IV) chloroform monosolvate

Md Abu Affan, Md Abdus Salam, Yang Farina Abdul Aziz, Seik Weng Ng

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The monodeprotonated Schiff base ligand in the title compound, [Sn(C 4H9)(C19H21N4S)Cl 2]·CHCl3, N,N′,S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the butyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain propagating in [010]. The Cl and H atoms of the chloro-form molecule are disordered over two positions in an 0.67:0.33 ratio.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number5
DOIs
Publication statusPublished - 14 Apr 2010

Fingerprint

Tin
Chloroform
Chlorine compounds
chloroform
methylene
tin
Atoms
atoms
Hydrogen bonds
hydrogen bonds
Molecules
Schiff Bases
chelates
imines
molecules
Ligands
ligands

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

@article{22100fe3f771401aa9461b50dcd38d06,
title = "N-Butyldichlorido{4-cyclohexyl-1-[phenyl(2-pyridyl-N)methylene] -thiosemicarbazidato-κ2N1,S}tin(IV) chloroform monosolvate",
abstract = "The monodeprotonated Schiff base ligand in the title compound, [Sn(C 4H9)(C19H21N4S)Cl 2]·CHCl3, N,N′,S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the butyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain propagating in [010]. The Cl and H atoms of the chloro-form molecule are disordered over two positions in an 0.67:0.33 ratio.",
author = "Affan, {Md Abu} and Salam, {Md Abdus} and {Abdul Aziz}, {Yang Farina} and Ng, {Seik Weng}",
year = "2010",
month = "4",
day = "14",
doi = "10.1107/S1600536810014455",
language = "English",
volume = "66",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "5",

}

TY - JOUR

T1 - N-Butyldichlorido{4-cyclohexyl-1-[phenyl(2-pyridyl-N)methylene] -thiosemicarbazidato-κ2N1,S}tin(IV) chloroform monosolvate

AU - Affan, Md Abu

AU - Salam, Md Abdus

AU - Abdul Aziz, Yang Farina

AU - Ng, Seik Weng

PY - 2010/4/14

Y1 - 2010/4/14

N2 - The monodeprotonated Schiff base ligand in the title compound, [Sn(C 4H9)(C19H21N4S)Cl 2]·CHCl3, N,N′,S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the butyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain propagating in [010]. The Cl and H atoms of the chloro-form molecule are disordered over two positions in an 0.67:0.33 ratio.

AB - The monodeprotonated Schiff base ligand in the title compound, [Sn(C 4H9)(C19H21N4S)Cl 2]·CHCl3, N,N′,S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the butyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain propagating in [010]. The Cl and H atoms of the chloro-form molecule are disordered over two positions in an 0.67:0.33 ratio.

UR - http://www.scopus.com/inward/record.url?scp=77952023992&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77952023992&partnerID=8YFLogxK

U2 - 10.1107/S1600536810014455

DO - 10.1107/S1600536810014455

M3 - Article

VL - 66

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 5

ER -