N-(Biphenyl-4-carbonyl)-N′-(4-chlorophenyl)thiourea

Bohari Mohd. Yamin, M. Asyikin M Arif

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

In the title compound, C20H15ClN2OS, the benzene rings of the biphenyl group are at an angle of 44.23 (12)°. The C4N2OS central thio-urea fragment makes dihedral angles with the benzene carbonyl and chloro-benzene rings of 55.96 (9) and 64.09 (9)°, respectively. The trans-cis geometry of the thio-urea group is stabilized by the intra-molecular hydrogen bond between the carbonyl O atom and the H atom of the cis-thio-amide. In the crystal structure, mol-ecules are linked by N - H⋯S and N - H⋯O inter-molecular hydrogen bonds to form one-dimensional chains along the c axis. C - H⋯π inter-actions also contribute to the stability of the mol-ecule.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number1
DOIs
Publication statusPublished - 2008

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Thiourea
Thioureas
thioureas
Benzene
benzene
ureas
Urea
Hydrogen
Hydrogen bonds
hydrogen bonds
Atoms
rings
Dihedral angle
Amides
amides
atoms
dihedral angle
Crystal structure
fragments
crystal structure

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

N-(Biphenyl-4-carbonyl)-N′-(4-chlorophenyl)thiourea. / Mohd. Yamin, Bohari; Arif, M. Asyikin M.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 64, No. 1, 2008.

Research output: Contribution to journalArticle

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