N-(Biphenyl-4-carbon-yl)-N′-(2-chloro-phen-yl)thio-urea

M. Asyikin M Arif, Bohari Mohd. Yamin

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

In the title compound, C20H15ClN2OS, the benzene rings of the biphenyl group are not coplanar, indicated by a dihedral angle of 20.71 (17)°. The mol-ecule maintains its trans-cis configuration with respect to the position of the biphenyl-carbonyl and chloro-benzene groups relative to the thiono S atom across their C - N bonds, respectively. The central carbonyl-thio-urea unit makes dihedral angles with the carbonyl benzene ring and the chloro-benzene fragment of 24.39 (13) and 61.63 (10)°, respectively. There is an intra-molecular N - H⋯O hydrogen bond in the mol-ecule. The mol-ecules in the structure are packed by weak van der Waals and π-π inter-actions [centroid-centroid distance 3.629 (2) Å].

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number8
DOIs
Publication statusPublished - 31 Jul 2007

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Benzene
ureas
Urea
Carbon
benzene
carbon
Dihedral angle
centroids
dihedral angle
rings
Hydrogen
Hydrogen bonds
fragments
hydrogen bonds
Atoms
diphenyl
configurations
atoms

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

N-(Biphenyl-4-carbon-yl)-N′-(2-chloro-phen-yl)thio-urea. / Arif, M. Asyikin M; Mohd. Yamin, Bohari.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 8, 31.07.2007.

Research output: Contribution to journalArticle

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abstract = "In the title compound, C20H15ClN2OS, the benzene rings of the biphenyl group are not coplanar, indicated by a dihedral angle of 20.71 (17)°. The mol-ecule maintains its trans-cis configuration with respect to the position of the biphenyl-carbonyl and chloro-benzene groups relative to the thiono S atom across their C - N bonds, respectively. The central carbonyl-thio-urea unit makes dihedral angles with the carbonyl benzene ring and the chloro-benzene fragment of 24.39 (13) and 61.63 (10)°, respectively. There is an intra-molecular N - H⋯O hydrogen bond in the mol-ecule. The mol-ecules in the structure are packed by weak van der Waals and π-π inter-actions [centroid-centroid distance 3.629 (2) {\AA}].",
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N2 - In the title compound, C20H15ClN2OS, the benzene rings of the biphenyl group are not coplanar, indicated by a dihedral angle of 20.71 (17)°. The mol-ecule maintains its trans-cis configuration with respect to the position of the biphenyl-carbonyl and chloro-benzene groups relative to the thiono S atom across their C - N bonds, respectively. The central carbonyl-thio-urea unit makes dihedral angles with the carbonyl benzene ring and the chloro-benzene fragment of 24.39 (13) and 61.63 (10)°, respectively. There is an intra-molecular N - H⋯O hydrogen bond in the mol-ecule. The mol-ecules in the structure are packed by weak van der Waals and π-π inter-actions [centroid-centroid distance 3.629 (2) Å].

AB - In the title compound, C20H15ClN2OS, the benzene rings of the biphenyl group are not coplanar, indicated by a dihedral angle of 20.71 (17)°. The mol-ecule maintains its trans-cis configuration with respect to the position of the biphenyl-carbonyl and chloro-benzene groups relative to the thiono S atom across their C - N bonds, respectively. The central carbonyl-thio-urea unit makes dihedral angles with the carbonyl benzene ring and the chloro-benzene fragment of 24.39 (13) and 61.63 (10)°, respectively. There is an intra-molecular N - H⋯O hydrogen bond in the mol-ecule. The mol-ecules in the structure are packed by weak van der Waals and π-π inter-actions [centroid-centroid distance 3.629 (2) Å].

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