(N-Benzyl-N-isopropyldithiocarbamato)chloridodiphenyltin(IV)

Amirah Faizah Abdul Muthalib, Ibrahim Baba, Mohamed Ibrahim Mohamed Tahir, Seik Weng Ng, Edward R T Tiekink

    Research output: Contribution to journalArticle

    4 Citations (Scopus)

    Abstract

    The SnIV atom in the title organotin dithio-carbamate, [Sn(C6H5)2(C11H14NS 2)Cl], is penta-coordinated by an asymmetrically coordinating dithio-carbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intra-molecular C-H⋯Cl and C-H⋯S contacts precludes the Cl and S atoms from forming significant inter-molecular contacts. The presence of C-H⋯π contacts leads to the formation of supra-molecular arrays that stack along the b axis.

    Original languageEnglish
    JournalActa Crystallographica Section E: Structure Reports Online
    Volume66
    Issue number9
    DOIs
    Publication statusPublished - Sep 2010

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    Carbamates
    Atoms
    atoms
    tendencies
    Ligands
    ligands
    Geometry
    geometry

    ASJC Scopus subject areas

    • Condensed Matter Physics
    • Materials Science(all)
    • Chemistry(all)

    Cite this

    (N-Benzyl-N-isopropyldithiocarbamato)chloridodiphenyltin(IV). / Abdul Muthalib, Amirah Faizah; Baba, Ibrahim; Mohamed Tahir, Mohamed Ibrahim; Ng, Seik Weng; Tiekink, Edward R T.

    In: Acta Crystallographica Section E: Structure Reports Online, Vol. 66, No. 9, 09.2010.

    Research output: Contribution to journalArticle

    Abdul Muthalib, Amirah Faizah ; Baba, Ibrahim ; Mohamed Tahir, Mohamed Ibrahim ; Ng, Seik Weng ; Tiekink, Edward R T. / (N-Benzyl-N-isopropyldithiocarbamato)chloridodiphenyltin(IV). In: Acta Crystallographica Section E: Structure Reports Online. 2010 ; Vol. 66, No. 9.
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    AU - Abdul Muthalib, Amirah Faizah

    AU - Baba, Ibrahim

    AU - Mohamed Tahir, Mohamed Ibrahim

    AU - Ng, Seik Weng

    AU - Tiekink, Edward R T

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    AB - The SnIV atom in the title organotin dithio-carbamate, [Sn(C6H5)2(C11H14NS 2)Cl], is penta-coordinated by an asymmetrically coordinating dithio-carbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intra-molecular C-H⋯Cl and C-H⋯S contacts precludes the Cl and S atoms from forming significant inter-molecular contacts. The presence of C-H⋯π contacts leads to the formation of supra-molecular arrays that stack along the b axis.

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