N′-benzoyl-N-p-bromophenylthiourea

Bohari Mohd. Yamin, M. Sukeri M Yusof

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

In the title compound, C14H11BrN2OS, the bromophenyl and benzoyl groups lie cis and trans, respectively, to the S atom across the thiourea C-N bonds. Owing to the presence of the Br atom in the para position, the dihedral angle between the bromophenyl group and the central carbonylthiourea plane is increased to 20.40 (11)°, in comparison with 7.52 (9)° in its unsubstituted phenyl analogue. The molecules are linked by intermolecular contacts N-H⋯S and C-H⋯O to form linear chains parallel to the a axis.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number3
DOIs
Publication statusPublished - Mar 2003

Fingerprint

Thiourea
Atoms
Thioureas
thioureas
Dihedral angle
atoms
dihedral angle
analogs
Molecules
molecules

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

N′-benzoyl-N-p-bromophenylthiourea. / Mohd. Yamin, Bohari; Yusof, M. Sukeri M.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, No. 3, 03.2003.

Research output: Contribution to journalArticle

@article{4e17d0720502449f85dfd4bea09050d6,
title = "N′-benzoyl-N-p-bromophenylthiourea",
abstract = "In the title compound, C14H11BrN2OS, the bromophenyl and benzoyl groups lie cis and trans, respectively, to the S atom across the thiourea C-N bonds. Owing to the presence of the Br atom in the para position, the dihedral angle between the bromophenyl group and the central carbonylthiourea plane is increased to 20.40 (11)°, in comparison with 7.52 (9)° in its unsubstituted phenyl analogue. The molecules are linked by intermolecular contacts N-H⋯S and C-H⋯O to form linear chains parallel to the a axis.",
author = "{Mohd. Yamin}, Bohari and Yusof, {M. Sukeri M}",
year = "2003",
month = "3",
doi = "10.1107/S1600536803003453",
language = "English",
volume = "59",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "3",

}

TY - JOUR

T1 - N′-benzoyl-N-p-bromophenylthiourea

AU - Mohd. Yamin, Bohari

AU - Yusof, M. Sukeri M

PY - 2003/3

Y1 - 2003/3

N2 - In the title compound, C14H11BrN2OS, the bromophenyl and benzoyl groups lie cis and trans, respectively, to the S atom across the thiourea C-N bonds. Owing to the presence of the Br atom in the para position, the dihedral angle between the bromophenyl group and the central carbonylthiourea plane is increased to 20.40 (11)°, in comparison with 7.52 (9)° in its unsubstituted phenyl analogue. The molecules are linked by intermolecular contacts N-H⋯S and C-H⋯O to form linear chains parallel to the a axis.

AB - In the title compound, C14H11BrN2OS, the bromophenyl and benzoyl groups lie cis and trans, respectively, to the S atom across the thiourea C-N bonds. Owing to the presence of the Br atom in the para position, the dihedral angle between the bromophenyl group and the central carbonylthiourea plane is increased to 20.40 (11)°, in comparison with 7.52 (9)° in its unsubstituted phenyl analogue. The molecules are linked by intermolecular contacts N-H⋯S and C-H⋯O to form linear chains parallel to the a axis.

UR - http://www.scopus.com/inward/record.url?scp=4444316570&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=4444316570&partnerID=8YFLogxK

U2 - 10.1107/S1600536803003453

DO - 10.1107/S1600536803003453

M3 - Article

VL - 59

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 3

ER -