N-[2-(diphenylphosphanyl)benzylidene]-4-methylaniline

Mustaffa Shamsuddin, Abdul Malik M Nur, Bohari Mohd. Yamin

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The title compound, C26H22NP, is a Schiff base derived from triphenylphosphine with a 4-methylphenylamine group attached to one of the benzene rings of the phosphine in the o-position. The azomethine C=N bond length is 1.259 (3) A and the dihedral angle between the benzene ring and its 4-methylphenylamine substituent is 40.02 (2) Å. The geometry at the P atom is approximately tetrahedral.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number7
DOIs
Publication statusPublished - 1 Jul 2005

Fingerprint

phosphine
Benzene
benzene
Schiff Bases
rings
Bond length
Dihedral angle
phosphines
imines
dihedral angle
Atoms
Geometry
geometry
atoms
methylaniline
azomethine
triphenylphosphine

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

N-[2-(diphenylphosphanyl)benzylidene]-4-methylaniline. / Shamsuddin, Mustaffa; Nur, Abdul Malik M; Mohd. Yamin, Bohari.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 61, No. 7, 01.07.2005.

Research output: Contribution to journalArticle

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AB - The title compound, C26H22NP, is a Schiff base derived from triphenylphosphine with a 4-methylphenylamine group attached to one of the benzene rings of the phosphine in the o-position. The azomethine C=N bond length is 1.259 (3) A and the dihedral angle between the benzene ring and its 4-methylphenylamine substituent is 40.02 (2) Å. The geometry at the P atom is approximately tetrahedral.

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