Lone pairs in confrontation in [M(S.CS.XR(n))3] systems. Crystal and molecular structure of tris(N-methyl-N-phenyldithiocarbamato) antimony(III)

Ibrahim Bin Baba, Brian W. Skelton, Allan H. White

    Research output: Contribution to journalArticle

    7 Citations (Scopus)

    Abstract

    Tris(dithiochelate) complexes of group 15 metals may crystallize with the metal atom disposed on a 3̄-axis confronting its inversion image (the title compound, shown, being the first such dithiocarbamate thus defined). The confrontation of the associated 'lone pairs' leads to interesting speculation as to the packing forces in play. Structural features, e.g.. M⋯M distances, are examined for the available examples.

    Original languageEnglish
    Pages (from-to)27-29+ii
    JournalAustralian Journal of Chemistry
    Volume56
    Issue number1
    DOIs
    Publication statusPublished - 2003

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    Antimony
    Molecular structure
    Crystal structure
    Metals
    Atoms

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Lone pairs in confrontation in [M(S.CS.XR(n))3] systems. Crystal and molecular structure of tris(N-methyl-N-phenyldithiocarbamato) antimony(III). / Bin Baba, Ibrahim; Skelton, Brian W.; White, Allan H.

    In: Australian Journal of Chemistry, Vol. 56, No. 1, 2003, p. 27-29+ii.

    Research output: Contribution to journalArticle

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