Induced photodegradation effect on the functionalized FE(III) complex additive-poly(Vinyl Chloride) thin film

Emad Yousif, Raghad Haddad, Badrul Hisyam Yahya, Syazwan Aizad, Noraziani Zainal Abidin, Hazreen Omar, Ili Afiqa Ab Kadir, Hasniza Zaman Huri, Bashar Mudhaffar Abdullah, Saiful Irwan Zubairi

Research output: Contribution to journalArticle

Abstract

A complex of Fe(III) with 4-amino-5-(pyridyl)-4H-1,2,4-triazole-3-thiol was prepared and evaluated as a photodegradation for polyvinyl chloride (PVC). Polyvinyl chloride was dissolved in THF solvent (5%, w/w) and functionalized with Fe (III) complex to form PVC films by means of solvent-casting method with a thickness of 40 μm. To study the effectiveness of Fe (III) complex additive, different concentrations (0.01, 0.02, 0.03, 0.04 and 0.05 g) were introduced into the PVC solution. The films’ photodegradation was investigated; the photodegradation activity of the compounds was determined by monitoring the carbonyl group, weight loss method and morphological study with irradiation time. The obtained experimental results showed that the additive behaved successfully as a photoinducer for the degradation process for the PVC films and the photooxidation rate increased with the increase of additive concentration.

Original languageEnglish
Pages (from-to)91-97
Number of pages7
JournalJurnal Teknologi
Volume78
Issue number7
DOIs
Publication statusPublished - 1 Jul 2016

Fingerprint

Photodegradation
Polyvinyl chlorides
Thin films
Photooxidation
Casting
Irradiation
Degradation
Monitoring

Keywords

  • Fe(III) complex
  • Photochemistry
  • Photooxidation
  • PVC

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Induced photodegradation effect on the functionalized FE(III) complex additive-poly(Vinyl Chloride) thin film. / Yousif, Emad; Haddad, Raghad; Yahya, Badrul Hisyam; Aizad, Syazwan; Abidin, Noraziani Zainal; Omar, Hazreen; Kadir, Ili Afiqa Ab; Huri, Hasniza Zaman; Abdullah, Bashar Mudhaffar; Zubairi, Saiful Irwan.

In: Jurnal Teknologi, Vol. 78, No. 7, 01.07.2016, p. 91-97.

Research output: Contribution to journalArticle

Yousif, E, Haddad, R, Yahya, BH, Aizad, S, Abidin, NZ, Omar, H, Kadir, IAA, Huri, HZ, Abdullah, BM & Zubairi, SI 2016, 'Induced photodegradation effect on the functionalized FE(III) complex additive-poly(Vinyl Chloride) thin film', Jurnal Teknologi, vol. 78, no. 7, pp. 91-97. https://doi.org/10.11113/jt.v78.4774
Yousif, Emad ; Haddad, Raghad ; Yahya, Badrul Hisyam ; Aizad, Syazwan ; Abidin, Noraziani Zainal ; Omar, Hazreen ; Kadir, Ili Afiqa Ab ; Huri, Hasniza Zaman ; Abdullah, Bashar Mudhaffar ; Zubairi, Saiful Irwan. / Induced photodegradation effect on the functionalized FE(III) complex additive-poly(Vinyl Chloride) thin film. In: Jurnal Teknologi. 2016 ; Vol. 78, No. 7. pp. 91-97.
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