Immobilization and characterizations of imidazolium-based ionic liquid on silica for CO2 adsorption/desorption studies

Tengku Sharifah Marliza Tengku Azmi, Mohd. Ambar Yarmo, Azizul Hakim, Maratun Najiha Abu Tahari, Taufiq Yap Yun Hin

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Supported imidazolium-based ionic liquids (ILs) were developed for adsorption/desorption studies of carbon dioxide. ILs could be easily immobilized into silica support materials using sol-gel method. The developed materials were successfully characterized using XRD, TGA, DTA, and BET analysis. The CO2 adsorption/desorption measurement were carried out using temperature-program-desorption technique and proved that the supported ILs on silica could reduce the temperature of CO2 desorption from 750 to 390 °C. The best performance for CO2 sorption (1.17 mmol CO2/g adsorbent) was achieved with 1-ethyl-3-methylimidazolium hydrogensulfate [EMIm][HSO4]-silica system.

Original languageEnglish
Title of host publicationMaterials Science Forum
PublisherTrans Tech Publications Ltd
Pages404-409
Number of pages6
Volume840
ISBN (Print)9783038355373
DOIs
Publication statusPublished - 2016
EventSeminar on Advanced Materials haracterization Techniques in Research, Industry and Nuclear Applications, AMCT 2015 - Selangor, Malaysia
Duration: 9 Jun 201510 Jun 2015

Publication series

NameMaterials Science Forum
Volume840
ISSN (Print)02555476

Other

OtherSeminar on Advanced Materials haracterization Techniques in Research, Industry and Nuclear Applications, AMCT 2015
CountryMalaysia
CitySelangor
Period9/6/1510/6/15

Fingerprint

Ionic Liquids
immobilization
Ionic liquids
Silicon Dioxide
Desorption
desorption
Silica
silicon dioxide
Adsorption
adsorption
liquids
adsorbents
Carbon Dioxide
sorption
Adsorbents
Differential thermal analysis
Sol-gel process
Sorption
carbon dioxide
Carbon dioxide

Keywords

  • Carbon dioxide
  • Ddsorption/desorption
  • Imidazolium
  • Immobilization
  • Ionic liquid

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering
  • Mechanics of Materials

Cite this

Tengku Azmi, T. S. M., Yarmo, M. A., Hakim, A., Abu Tahari, M. N., & Yun Hin, T. Y. (2016). Immobilization and characterizations of imidazolium-based ionic liquid on silica for CO2 adsorption/desorption studies. In Materials Science Forum (Vol. 840, pp. 404-409). (Materials Science Forum; Vol. 840). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/MSF.840.404

Immobilization and characterizations of imidazolium-based ionic liquid on silica for CO2 adsorption/desorption studies. / Tengku Azmi, Tengku Sharifah Marliza; Yarmo, Mohd. Ambar; Hakim, Azizul; Abu Tahari, Maratun Najiha; Yun Hin, Taufiq Yap.

Materials Science Forum. Vol. 840 Trans Tech Publications Ltd, 2016. p. 404-409 (Materials Science Forum; Vol. 840).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Tengku Azmi, TSM, Yarmo, MA, Hakim, A, Abu Tahari, MN & Yun Hin, TY 2016, Immobilization and characterizations of imidazolium-based ionic liquid on silica for CO2 adsorption/desorption studies. in Materials Science Forum. vol. 840, Materials Science Forum, vol. 840, Trans Tech Publications Ltd, pp. 404-409, Seminar on Advanced Materials haracterization Techniques in Research, Industry and Nuclear Applications, AMCT 2015, Selangor, Malaysia, 9/6/15. https://doi.org/10.4028/www.scientific.net/MSF.840.404
Tengku Azmi TSM, Yarmo MA, Hakim A, Abu Tahari MN, Yun Hin TY. Immobilization and characterizations of imidazolium-based ionic liquid on silica for CO2 adsorption/desorption studies. In Materials Science Forum. Vol. 840. Trans Tech Publications Ltd. 2016. p. 404-409. (Materials Science Forum). https://doi.org/10.4028/www.scientific.net/MSF.840.404
Tengku Azmi, Tengku Sharifah Marliza ; Yarmo, Mohd. Ambar ; Hakim, Azizul ; Abu Tahari, Maratun Najiha ; Yun Hin, Taufiq Yap. / Immobilization and characterizations of imidazolium-based ionic liquid on silica for CO2 adsorption/desorption studies. Materials Science Forum. Vol. 840 Trans Tech Publications Ltd, 2016. pp. 404-409 (Materials Science Forum).
@inproceedings{6893ee52eda04c46b02d41d55e04f030,
title = "Immobilization and characterizations of imidazolium-based ionic liquid on silica for CO2 adsorption/desorption studies",
abstract = "Supported imidazolium-based ionic liquids (ILs) were developed for adsorption/desorption studies of carbon dioxide. ILs could be easily immobilized into silica support materials using sol-gel method. The developed materials were successfully characterized using XRD, TGA, DTA, and BET analysis. The CO2 adsorption/desorption measurement were carried out using temperature-program-desorption technique and proved that the supported ILs on silica could reduce the temperature of CO2 desorption from 750 to 390 °C. The best performance for CO2 sorption (1.17 mmol CO2/g adsorbent) was achieved with 1-ethyl-3-methylimidazolium hydrogensulfate [EMIm][HSO4]-silica system.",
keywords = "Carbon dioxide, Ddsorption/desorption, Imidazolium, Immobilization, Ionic liquid",
author = "{Tengku Azmi}, {Tengku Sharifah Marliza} and Yarmo, {Mohd. Ambar} and Azizul Hakim and {Abu Tahari}, {Maratun Najiha} and {Yun Hin}, {Taufiq Yap}",
year = "2016",
doi = "10.4028/www.scientific.net/MSF.840.404",
language = "English",
isbn = "9783038355373",
volume = "840",
series = "Materials Science Forum",
publisher = "Trans Tech Publications Ltd",
pages = "404--409",
booktitle = "Materials Science Forum",

}

TY - GEN

T1 - Immobilization and characterizations of imidazolium-based ionic liquid on silica for CO2 adsorption/desorption studies

AU - Tengku Azmi, Tengku Sharifah Marliza

AU - Yarmo, Mohd. Ambar

AU - Hakim, Azizul

AU - Abu Tahari, Maratun Najiha

AU - Yun Hin, Taufiq Yap

PY - 2016

Y1 - 2016

N2 - Supported imidazolium-based ionic liquids (ILs) were developed for adsorption/desorption studies of carbon dioxide. ILs could be easily immobilized into silica support materials using sol-gel method. The developed materials were successfully characterized using XRD, TGA, DTA, and BET analysis. The CO2 adsorption/desorption measurement were carried out using temperature-program-desorption technique and proved that the supported ILs on silica could reduce the temperature of CO2 desorption from 750 to 390 °C. The best performance for CO2 sorption (1.17 mmol CO2/g adsorbent) was achieved with 1-ethyl-3-methylimidazolium hydrogensulfate [EMIm][HSO4]-silica system.

AB - Supported imidazolium-based ionic liquids (ILs) were developed for adsorption/desorption studies of carbon dioxide. ILs could be easily immobilized into silica support materials using sol-gel method. The developed materials were successfully characterized using XRD, TGA, DTA, and BET analysis. The CO2 adsorption/desorption measurement were carried out using temperature-program-desorption technique and proved that the supported ILs on silica could reduce the temperature of CO2 desorption from 750 to 390 °C. The best performance for CO2 sorption (1.17 mmol CO2/g adsorbent) was achieved with 1-ethyl-3-methylimidazolium hydrogensulfate [EMIm][HSO4]-silica system.

KW - Carbon dioxide

KW - Ddsorption/desorption

KW - Imidazolium

KW - Immobilization

KW - Ionic liquid

UR - http://www.scopus.com/inward/record.url?scp=84958093005&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84958093005&partnerID=8YFLogxK

U2 - 10.4028/www.scientific.net/MSF.840.404

DO - 10.4028/www.scientific.net/MSF.840.404

M3 - Conference contribution

SN - 9783038355373

VL - 840

T3 - Materials Science Forum

SP - 404

EP - 409

BT - Materials Science Forum

PB - Trans Tech Publications Ltd

ER -