Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride

Karen A. Crouse, Kar Teng Chew, Bohari Mohd. Yamin, Seik Weng Ng, M. T H Tarafder

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The title compound, [C7H10N3S 2]+-Cl-, exists as an ionic compound of a dithiocarbazate system, with a zwitterionic +H3NNCS - moiety and a protonated pyridine ring. The C-S thione bond distance of the zwitterionic moiety [1.708 (2) Å] is longer than the normal double bond and the C-N of the carbazate moiety has double-bond character. The crystal packing is stabilized by intramolecular hydrogen bonds, which form a two-dimensional network perpendicular to b.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number2
DOIs
Publication statusPublished - Feb 2003

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hydrazine
Methyl Chloride
Thiones
Hydrazine
hydrazines
Pyridine
Chlorides
esters
Hydrogen
pyridines
Esters
Hydrogen bonds
chlorides
hydrogen bonds
Crystals
acids
Acids
rings
crystals
pyridine

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. / Crouse, Karen A.; Chew, Kar Teng; Mohd. Yamin, Bohari; Ng, Seik Weng; Tarafder, M. T H.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, No. 2, 02.2003.

Research output: Contribution to journalArticle

Crouse, Karen A. ; Chew, Kar Teng ; Mohd. Yamin, Bohari ; Ng, Seik Weng ; Tarafder, M. T H. / Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. In: Acta Crystallographica Section E: Structure Reports Online. 2003 ; Vol. 59, No. 2.
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