Functional 2-benzyl-1,2-dihydro[60]fullerenes as acceptors for organic photovoltaics: Facile synthesis and high photovoltaic performances

Shirong Lu, Tienan Jin, Takeshi Yasuda, Ashraful Islam, Md Akhtaruzzaman, Liyuan Han, Khalid A. Alamry, Samia A. Kosa, Abdullah Mohamed Asiri, Yoshinori Yamamoto

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A new series of functional 2-benzyl-1,2-dihydro[60]fullerenes, BnHCs, were synthesized efficiently via co-catalyzed selective monofunctionalization of C60 with functional benzyl bromides. Photophysical and electrochemical properties of the new BnHCs were investigated. PSCs based on 2-MeO-4-CO2Me-BnHC as new acceptor and P3HT as donor showed a power conversion efficiency of 3.75%, which is comparable to that of PC61BM under the same device conditions.

Original languageEnglish
Pages (from-to)1302-1306
Number of pages5
JournalTetrahedron
Volume69
Issue number4
DOIs
Publication statusPublished - 28 Jan 2013
Externally publishedYes

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Electrochemical properties
Conversion efficiency
Equipment and Supplies
fullerene C60
benzyl bromide

Keywords

  • Catalytic synthesis
  • Fullerene acceptor
  • Mono-functional benzyl
  • Polymer solar cells
  • Power conversion efficiency

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Functional 2-benzyl-1,2-dihydro[60]fullerenes as acceptors for organic photovoltaics : Facile synthesis and high photovoltaic performances. / Lu, Shirong; Jin, Tienan; Yasuda, Takeshi; Islam, Ashraful; Akhtaruzzaman, Md; Han, Liyuan; Alamry, Khalid A.; Kosa, Samia A.; Asiri, Abdullah Mohamed; Yamamoto, Yoshinori.

In: Tetrahedron, Vol. 69, No. 4, 28.01.2013, p. 1302-1306.

Research output: Contribution to journalArticle

Lu, Shirong ; Jin, Tienan ; Yasuda, Takeshi ; Islam, Ashraful ; Akhtaruzzaman, Md ; Han, Liyuan ; Alamry, Khalid A. ; Kosa, Samia A. ; Asiri, Abdullah Mohamed ; Yamamoto, Yoshinori. / Functional 2-benzyl-1,2-dihydro[60]fullerenes as acceptors for organic photovoltaics : Facile synthesis and high photovoltaic performances. In: Tetrahedron. 2013 ; Vol. 69, No. 4. pp. 1302-1306.
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AU - Jin, Tienan

AU - Yasuda, Takeshi

AU - Islam, Ashraful

AU - Akhtaruzzaman, Md

AU - Han, Liyuan

AU - Alamry, Khalid A.

AU - Kosa, Samia A.

AU - Asiri, Abdullah Mohamed

AU - Yamamoto, Yoshinori

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