Ferrocenium tetrachloroantimonate

Bohari Mohd. Yamin, Hoong Kun Fun, Kandasamy Sivakumar, Boon Chuan Yip, Omar Bin Shawkataly

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The crystal structure of ferrocenium tetrachloroantimonate, [Fe(C5H5)2][SbCl4], has been determined at 173 K. The cyclopentadiene rings in the ferrocenium cation are in an eclipsed conformation. The Sb atom is coordinated by six Cl ions in an irregular octahedral arrangement. Two Cl- ions form halogen bridges with neighbouring Sb atoms, resulting in a polymeric chain of anions {the compound may be named catena-poly[ferrocinium (dichloroantimonate-diμ-chloro)]}. The ferrocenium cations are stacked between these polymeric chains and form two-dimensional layers parallel to the bc plane.

Original languageEnglish
Pages (from-to)600-602
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number3
Publication statusPublished - 15 Mar 1996

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halogens
Ions
atoms
Cyclopentanes
Atoms
ions
Halogens
anions
crystal structure
Anions
Conformations
rings
Crystal structure
ferrocenium

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Mohd. Yamin, B., Fun, H. K., Sivakumar, K., Yip, B. C., & Bin Shawkataly, O. (1996). Ferrocenium tetrachloroantimonate. Acta Crystallographica Section C: Crystal Structure Communications, 52(3), 600-602.

Ferrocenium tetrachloroantimonate. / Mohd. Yamin, Bohari; Fun, Hoong Kun; Sivakumar, Kandasamy; Yip, Boon Chuan; Bin Shawkataly, Omar.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 52, No. 3, 15.03.1996, p. 600-602.

Research output: Contribution to journalArticle

Mohd. Yamin, B, Fun, HK, Sivakumar, K, Yip, BC & Bin Shawkataly, O 1996, 'Ferrocenium tetrachloroantimonate', Acta Crystallographica Section C: Crystal Structure Communications, vol. 52, no. 3, pp. 600-602.
Mohd. Yamin B, Fun HK, Sivakumar K, Yip BC, Bin Shawkataly O. Ferrocenium tetrachloroantimonate. Acta Crystallographica Section C: Crystal Structure Communications. 1996 Mar 15;52(3):600-602.
Mohd. Yamin, Bohari ; Fun, Hoong Kun ; Sivakumar, Kandasamy ; Yip, Boon Chuan ; Bin Shawkataly, Omar. / Ferrocenium tetrachloroantimonate. In: Acta Crystallographica Section C: Crystal Structure Communications. 1996 ; Vol. 52, No. 3. pp. 600-602.
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