Experimental design using response surface methods for palm olein-based hydroxy-ether systhesis

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Hydroxy-ether-PO0 was synthesised via alcoholysis reaction of epoxidized palm olein (EPO0). The experimental design was conducted using response surface methodology (RSM) based on 3 factors; reaction time, reaction temperature and catalyst loading. Responses such as percentage of conversion and percentage of yield were determined using statistical software 'Design Expert 9'. Hydroxy-ether-PO0 showed the presence of proton peak attached to the carbon of ether (3.2, 3.5 ppm) and proton of the hydroxyl (4.8 ppm). The presence of carbon peak bonded to hydroxyl was detected at chemical shift 75 ppm and carbonyl carbon of ether at 72 ppm.

Original languageEnglish
Pages (from-to)1149-1154
Number of pages6
JournalSains Malaysiana
Volume45
Issue number7
Publication statusPublished - 1 Jul 2016

Fingerprint

Ether
Design of experiments
Carbon
Hydroxyl Radical
Protons
Chemical shift
Software design
Catalysts
Temperature

Keywords

  • Alcoholysis
  • Oxirane cleavage
  • Palm olein
  • Response surface methods

ASJC Scopus subject areas

  • General

Cite this

Experimental design using response surface methods for palm olein-based hydroxy-ether systhesis. / Derawi, Darfizzi.

In: Sains Malaysiana, Vol. 45, No. 7, 01.07.2016, p. 1149-1154.

Research output: Contribution to journalArticle

@article{7cb7739e01c2453995f2b0903b0d51d7,
title = "Experimental design using response surface methods for palm olein-based hydroxy-ether systhesis",
abstract = "Hydroxy-ether-PO0 was synthesised via alcoholysis reaction of epoxidized palm olein (EPO0). The experimental design was conducted using response surface methodology (RSM) based on 3 factors; reaction time, reaction temperature and catalyst loading. Responses such as percentage of conversion and percentage of yield were determined using statistical software 'Design Expert 9'. Hydroxy-ether-PO0 showed the presence of proton peak attached to the carbon of ether (3.2, 3.5 ppm) and proton of the hydroxyl (4.8 ppm). The presence of carbon peak bonded to hydroxyl was detected at chemical shift 75 ppm and carbonyl carbon of ether at 72 ppm.",
keywords = "Alcoholysis, Oxirane cleavage, Palm olein, Response surface methods",
author = "Darfizzi Derawi",
year = "2016",
month = "7",
day = "1",
language = "English",
volume = "45",
pages = "1149--1154",
journal = "Sains Malaysiana",
issn = "0126-6039",
publisher = "Penerbit Universiti Kebangsaan Malaysia",
number = "7",

}

TY - JOUR

T1 - Experimental design using response surface methods for palm olein-based hydroxy-ether systhesis

AU - Derawi, Darfizzi

PY - 2016/7/1

Y1 - 2016/7/1

N2 - Hydroxy-ether-PO0 was synthesised via alcoholysis reaction of epoxidized palm olein (EPO0). The experimental design was conducted using response surface methodology (RSM) based on 3 factors; reaction time, reaction temperature and catalyst loading. Responses such as percentage of conversion and percentage of yield were determined using statistical software 'Design Expert 9'. Hydroxy-ether-PO0 showed the presence of proton peak attached to the carbon of ether (3.2, 3.5 ppm) and proton of the hydroxyl (4.8 ppm). The presence of carbon peak bonded to hydroxyl was detected at chemical shift 75 ppm and carbonyl carbon of ether at 72 ppm.

AB - Hydroxy-ether-PO0 was synthesised via alcoholysis reaction of epoxidized palm olein (EPO0). The experimental design was conducted using response surface methodology (RSM) based on 3 factors; reaction time, reaction temperature and catalyst loading. Responses such as percentage of conversion and percentage of yield were determined using statistical software 'Design Expert 9'. Hydroxy-ether-PO0 showed the presence of proton peak attached to the carbon of ether (3.2, 3.5 ppm) and proton of the hydroxyl (4.8 ppm). The presence of carbon peak bonded to hydroxyl was detected at chemical shift 75 ppm and carbonyl carbon of ether at 72 ppm.

KW - Alcoholysis

KW - Oxirane cleavage

KW - Palm olein

KW - Response surface methods

UR - http://www.scopus.com/inward/record.url?scp=84983334798&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84983334798&partnerID=8YFLogxK

M3 - Article

VL - 45

SP - 1149

EP - 1154

JO - Sains Malaysiana

JF - Sains Malaysiana

SN - 0126-6039

IS - 7

ER -