Enhancement of plasticizing effect on bio-based polyurethane acrylate solid polymer electrolyte and its properties

Tuan Syarifah Rossyidah Naiwi, Min Min Aung, Azizan Ahmad, Marwah Rayung, Mohd Sukor Su'ait, Nor Azah Yusof, Khine Zar Wynn Lae

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Polyurethane acrylate (PUA) from vegetable oil has been synthesized and prepared for solid polymer electrolyte. Polyol has been end-capped with Toluene 2,4-Diisocyanate (TDI) followed by hydroxylethylmethylacrylate (HEMA) in a urethanation process to produce PUA. The mixtures were cured to make thin polymeric films under UV radiation to produce excellent cured films which exhibit good thermal stability and obtain high ionic conductivity value. 3 to 15 wt. % of ethylene carbonate (EC) mixed with 25 wt. %LiClO4 was added to PUA to obtain PUA electrolyte systems. PUA modified with plasticizer EC 9 wt. % achieved the highest conductivity of 7.86 × 10-4 S/cm, and relatively improved the linear sweep voltammetry, transference number and dielectric properties. Fourier Transform Infrared Spectroscopy (FTIR) and dielectric analysis were presented. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), followed by X-ray Diffraction (XRD) and morphology have been studied. The addition of plasticizer to the polyurethane acrylate shows significant improvement in terms of the conductivity and performance of the polymer electrolyte.

Original languageEnglish
Article number1142
JournalPolymers
Volume10
Issue number10
DOIs
Publication statusPublished - 12 Oct 2018

Fingerprint

Polyurethanes
Electrolytes
Polymers
Plasticizers
Carbonates
Ethylene
Toluene 2,4-Diisocyanate
Plant Oils
Vegetable oils
Polyols
Ionic conductivity
Voltammetry
Polymer films
Ultraviolet radiation
Dielectric properties
Fourier transform infrared spectroscopy
Toluene
Thermogravimetric analysis
acrylic acid
Differential scanning calorimetry

Keywords

  • Biopolymer electrolyte
  • Conductivity
  • Plasticizer
  • Polyurethane acrylate
  • Solid polymer

ASJC Scopus subject areas

  • Chemistry(all)
  • Polymers and Plastics

Cite this

Enhancement of plasticizing effect on bio-based polyurethane acrylate solid polymer electrolyte and its properties. / Naiwi, Tuan Syarifah Rossyidah; Aung, Min Min; Ahmad, Azizan; Rayung, Marwah; Su'ait, Mohd Sukor; Yusof, Nor Azah; Lae, Khine Zar Wynn.

In: Polymers, Vol. 10, No. 10, 1142, 12.10.2018.

Research output: Contribution to journalArticle

Naiwi, Tuan Syarifah Rossyidah ; Aung, Min Min ; Ahmad, Azizan ; Rayung, Marwah ; Su'ait, Mohd Sukor ; Yusof, Nor Azah ; Lae, Khine Zar Wynn. / Enhancement of plasticizing effect on bio-based polyurethane acrylate solid polymer electrolyte and its properties. In: Polymers. 2018 ; Vol. 10, No. 10.
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