Effects of ethylene glycol dimethacrylate as cross-linker in ionic liquid gel polymer electrolyte based on poly(glycidyl methacrylate)

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7 Citations (Scopus)

Abstract

In this study, modified poly(glycidyl methacrylate)-based films for gel electrolyte were prepared by an in situ UV photopolymerization technique. The effects of adding ethylene glycol dimethacrylate (EGDMA) to the polymer host were studied through X-ray diffraction analysis and differential scanning calorimetry. The results from Fourier transform-infrared spectra indicate complete polymerization among the monomers. The addition of EGDMA to the formulation of gel polymer electrolyte increased the loading of 1-butyl-3-methylimidazolium bis(fluoromethylsulfonyl)imide up to 200 wt.% with the highest value of 8.2 × 10−4 S cm−1. All the gel polymer electrolyte membranes obeyed the Arrhenius law.

Original languageEnglish
Pages (from-to)95-103
Number of pages9
JournalInternational Journal of Polymer Analysis and Characterization
Volume21
Issue number2
DOIs
Publication statusPublished - 17 Feb 2016

Fingerprint

Ionic Liquids
Ethylene glycol
Ionic liquids
Electrolytes
Polymers
Gels
Imides
Photopolymerization
X ray diffraction analysis
Differential scanning calorimetry
Fourier transforms
Monomers
Polymerization
Infrared radiation
Membranes
ethylene dimethacrylate
polyglycidyl methacrylate

Keywords

  • Cross-linker
  • ionic liquid
  • photopolymerization
  • polymer electrolyte

ASJC Scopus subject areas

  • Polymers and Plastics
  • Analytical Chemistry
  • Chemical Engineering(all)

Cite this

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title = "Effects of ethylene glycol dimethacrylate as cross-linker in ionic liquid gel polymer electrolyte based on poly(glycidyl methacrylate)",
abstract = "In this study, modified poly(glycidyl methacrylate)-based films for gel electrolyte were prepared by an in situ UV photopolymerization technique. The effects of adding ethylene glycol dimethacrylate (EGDMA) to the polymer host were studied through X-ray diffraction analysis and differential scanning calorimetry. The results from Fourier transform-infrared spectra indicate complete polymerization among the monomers. The addition of EGDMA to the formulation of gel polymer electrolyte increased the loading of 1-butyl-3-methylimidazolium bis(fluoromethylsulfonyl)imide up to 200 wt.{\%} with the highest value of 8.2 × 10−4 S cm−1. All the gel polymer electrolyte membranes obeyed the Arrhenius law.",
keywords = "Cross-linker, ionic liquid, photopolymerization, polymer electrolyte",
author = "Wong, {B. C F} and Azizan Ahmad and {Abu Hanifah}, Sharina and Hassan, {Nur Hasyareeda}",
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T1 - Effects of ethylene glycol dimethacrylate as cross-linker in ionic liquid gel polymer electrolyte based on poly(glycidyl methacrylate)

AU - Wong, B. C F

AU - Ahmad, Azizan

AU - Abu Hanifah, Sharina

AU - Hassan, Nur Hasyareeda

PY - 2016/2/17

Y1 - 2016/2/17

N2 - In this study, modified poly(glycidyl methacrylate)-based films for gel electrolyte were prepared by an in situ UV photopolymerization technique. The effects of adding ethylene glycol dimethacrylate (EGDMA) to the polymer host were studied through X-ray diffraction analysis and differential scanning calorimetry. The results from Fourier transform-infrared spectra indicate complete polymerization among the monomers. The addition of EGDMA to the formulation of gel polymer electrolyte increased the loading of 1-butyl-3-methylimidazolium bis(fluoromethylsulfonyl)imide up to 200 wt.% with the highest value of 8.2 × 10−4 S cm−1. All the gel polymer electrolyte membranes obeyed the Arrhenius law.

AB - In this study, modified poly(glycidyl methacrylate)-based films for gel electrolyte were prepared by an in situ UV photopolymerization technique. The effects of adding ethylene glycol dimethacrylate (EGDMA) to the polymer host were studied through X-ray diffraction analysis and differential scanning calorimetry. The results from Fourier transform-infrared spectra indicate complete polymerization among the monomers. The addition of EGDMA to the formulation of gel polymer electrolyte increased the loading of 1-butyl-3-methylimidazolium bis(fluoromethylsulfonyl)imide up to 200 wt.% with the highest value of 8.2 × 10−4 S cm−1. All the gel polymer electrolyte membranes obeyed the Arrhenius law.

KW - Cross-linker

KW - ionic liquid

KW - photopolymerization

KW - polymer electrolyte

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