Effects of CH3NH3Pbl(3-x)Clx perovskite layer on the performance of inverted type hybrid organic solar cells based on ZnO/P3HT

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

This paper reports the effect of perovskite layer on enhancing the inverted type hybrid organic solar cell performance. The mixtures of methylammonium iodide (CH3NH3I) and lead (II) chloride (PbCl2) were dissolved in N,N-Dimethylformamide (DMF) solvent and was spin-coated onto fluorine-doped tin oxide (FTO) glass substrate coated with zinc oxide nanorod arrays (ZnONRAs). The poly(3-hexylthiophene-2,5-diyl) (P3HT) film was then spin-coated onto CH3NH3I(3-x)PbClx perovskite layer, followed by silver (Ag) deposition using magnetron sputtering technique. The FTO/ZnO seed/ZnONRAs/CH3NH3PbI(3-x)Clx /P3HT/Ag device was fabricated. A device without perovskite layer was also fabricated for comparison. Power conversion efficiency (PCE) of 0.56% was achieved with the introduction of perovskite layer. The PCE was approximately six times greater than the device without perovskite layer, as a result of wider light absorption range and higher exciton dissociation efficiency.

Original languageEnglish
Title of host publicationMaterials Science Forum
PublisherTrans Tech Publications Ltd
Pages292-297
Number of pages6
Volume846
ISBN (Print)9783038357520
DOIs
Publication statusPublished - 2016
Event28th Regional Conference on Solid State Science and Technology, RCSSST 2014 - Cameron Highlands, Pahang, Malaysia
Duration: 25 Nov 201427 Nov 2014

Publication series

NameMaterials Science Forum
Volume846
ISSN (Print)02555476

Other

Other28th Regional Conference on Solid State Science and Technology, RCSSST 2014
CountryMalaysia
CityCameron Highlands, Pahang
Period25/11/1427/11/14

Fingerprint

Perovskite
solar cells
Zinc Oxide
Fluorine
Zinc oxide
Tin oxides
Nanorods
zinc oxides
tin oxides
nanorods
Conversion efficiency
fluorine
Dimethylformamide
Iodides
electromagnetic absorption
Silver
Excitons
Magnetron sputtering
Light absorption
iodides

Keywords

  • Organic solar cell
  • P3HT
  • Perovskite
  • ZnO nanorod arrays

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering
  • Mechanics of Materials

Cite this

Effects of CH3NH3Pbl(3-x)Clx perovskite layer on the performance of inverted type hybrid organic solar cells based on ZnO/P3HT. / Sabri, Nasehah Syamin; Yap, Chi Chin; Yahaya, Muhammad; Mat Salleh, Muhamad; Jumali, Mohammad Hafizuddin.

Materials Science Forum. Vol. 846 Trans Tech Publications Ltd, 2016. p. 292-297 (Materials Science Forum; Vol. 846).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Sabri, NS, Yap, CC, Yahaya, M, Mat Salleh, M & Jumali, MH 2016, Effects of CH3NH3Pbl(3-x)Clx perovskite layer on the performance of inverted type hybrid organic solar cells based on ZnO/P3HT. in Materials Science Forum. vol. 846, Materials Science Forum, vol. 846, Trans Tech Publications Ltd, pp. 292-297, 28th Regional Conference on Solid State Science and Technology, RCSSST 2014, Cameron Highlands, Pahang, Malaysia, 25/11/14. https://doi.org/10.4028/www.scientific.net/MSF.846.292
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AB - This paper reports the effect of perovskite layer on enhancing the inverted type hybrid organic solar cell performance. The mixtures of methylammonium iodide (CH3NH3I) and lead (II) chloride (PbCl2) were dissolved in N,N-Dimethylformamide (DMF) solvent and was spin-coated onto fluorine-doped tin oxide (FTO) glass substrate coated with zinc oxide nanorod arrays (ZnONRAs). The poly(3-hexylthiophene-2,5-diyl) (P3HT) film was then spin-coated onto CH3NH3I(3-x)PbClx perovskite layer, followed by silver (Ag) deposition using magnetron sputtering technique. The FTO/ZnO seed/ZnONRAs/CH3NH3PbI(3-x)Clx /P3HT/Ag device was fabricated. A device without perovskite layer was also fabricated for comparison. Power conversion efficiency (PCE) of 0.56% was achieved with the introduction of perovskite layer. The PCE was approximately six times greater than the device without perovskite layer, as a result of wider light absorption range and higher exciton dissociation efficiency.

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